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GCMS quantitation results for sample AE10241, May 2002

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Laboratory report documenting GCMS analysis of sample AE10241 conducted on May 28, 2002.

NYC-WTC_000024780–000024790

Folder label: “GCMS X 5/14/02 A 5/17/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\020509\10241.D Vial: 19 Acq On : 10 May 2002 4:25 am Operator: Nefliu Sample : sample Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: rteint.e

Quant Method : C:\MSDCHEM\1\METHODS\SCAN020507.M (RTE Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1 ********************************************************************* Peak Number 3 Phenanthrene-diO Concentration Rank 5

R.T. EstConc Area Relative to ISTD R.T. 31.96 0.35 ug/1 44176 Phenanthrene-dl0 31.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1Phenanthrene-d10 188 C14D10 001517-22-2 68 2 Anthracene-d10- 188 C14D10 001719-06-8 64 3 Phosphonic acid, (3-methyl-3-pen... 188 C8H13O3P 022152-34-7 43 4 Imidazole, 4-carboxy-5-phenyl-188 C10H8N2O2 1000116-63-8 35 Abundal Scan 4916 (31.963 min): 10241 .D (-4902) (-) m/z 188.15 100.00% 188

5000 80 — 160 92 31.60 31.80 32.00 32.20 40 52 64 102 114 126 146 1 - nlanl rh I | I > I ! | I I I I | I I I > | I I I I'l I M ■p-rrr m/z 80.05 22.39% TTT /z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79827: Phenanthrene-d10 188

5000 31.60 31.80 32.00 32.20 m/z 160.10 21.62% 80 94 160 30 42 52 66 11 108118 132 146 II 170179 TTTTITTTTTTTTTTTHTTTTHTTTTTT miz-> 10 20 30 40 50 60 70 80 90 100 110 120 1.30 140 150 160 170 180 190 Abundance #79826: Anthracene-d1 0- 188

31.60 31.80 32.00 32.20 5000 m/z 184.10 20.42%

80 94 160 ,|. 17 30 42 52 66 TIVWIWgtnmguTHH 108118 132 TT*m—utpudtutr 146.10,179179/,..., m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79704: Phosphonic acid, (3-methyl-3-penten-1 -ynyl)-, dime... Tf [ITIIIIEIIIIIII 188 31.60 31.80 32.00 32.20 m/z 187.20 19.08%

5000 77 62 91 109 155 173

m/z—> H 18 KJ ---m l.i I| 1 128 141 । 1...I 111" 11111,1!'11 1 r "' r1 ‘ r1" 10 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 31.60 31.80 32.00 32.20

10241.D SCAN020507.M Tue May 14 14:25:38 2002 Page 5

NYC-WTC_000024786

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NYC-WTC_000024786Source: NYC Law Department, mirrored locally

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