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GC/MS calibration report for TCLP method, Oct 2001

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Instrument calibration report for GC/MS Method NP091101 used for TCLP analysis, generated on October 16, 2001.

NYC-WTC_000088700–000088724

Folder label: “GC/MS Scan 9/27/01

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\HPCHEM\1\DATA\OCT1601\LB.D Vial: 3 Acq On : 16 Oct 2001 4:11 pm Operator: 209 GALOS Sample : lab blk 9/27 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP091101.M (RTE Integrator) Title : 209 625/TCLP calibration table 7/16/01 Library ; C:\DATABASE\NBS75K.L

Peak Number 5 Cyclopentanecarboxylic acid, 2 Concentration Rank 6 R.T. EstConc Area Relative to ISTD R.T. 29.50 1.43 ug/1 153162 Chrysene-dl2 33.12 Hit# of 5 Tj^ntative ID MW MolForm CAS# Qua!

1 Cyclopentafnecarboxylic acid, 2-amin 129 C6H11NO2 040482-05-1 38 2 Cyclopepxanecarboxylic acid, 2-amin 129 C6H11NO2 . 037910-65-9 32 3 Decan^ 2,2,3-trimethyl- 184 C13H28 062338-09-4 27 4 l-He/ene, 2-methyl- ______________ 98 C7H14 006094-02-6 27 . Abundance Scan 2665 (29.504 min): LB.D (-) m/z 56.00 100.00% 55

5000 41 73 257 .... ............. I 4Q-1 129

n/z-> 4^ X 312 T'-'+n m/z 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 239 29.20 29.40 29.60 29.80 57.00 52748% Abundance #5212: Cyclopentanecarboxylic acid, 2-amino-, trans- 53

5000 ' ' I ' ' 29.20 29.40 29.60 29.80 m/z 4370^ 41.84% 30 129 70 ax 100 I_________ ___ I'''' I'' I ■ 11 I'' ‘' I'''' I'''' I'''' I'''' I'''' I'''' I''' 11'''' I mZz-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 Abundance #5218: Cyclopentanecarboxylic acid. 2-amino-. cis- 53

29.20 29.40 29.60 29.80 gjilil in/z 41.05 38.75%

30 ?? ?4 . — - -- - - ---- ,1 , H ' ' ' I * ’ '' I ' ' ' ' I ' I ' I t * I ' * ' ' J ' • r.-| I . . . J n-r. j . . . r| m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 Abundance #19005: Decane, 2,2,3-trimethyl- 5(7 29.20 29.40 29.60 - 29.80 -r m/z 55.00 32.35%

5000

27 , 7 85 99 126 p-V-rryrT p-m-pY-r-rnYT-TV-Tyrh-Tn-p-T-TTp-TT-TyTT-rryTTTnq-Tn-TT^^ ' ' I ' ' ' ' I m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 29.20 29.40 29,60 29.80

LB.D NP091101.M Thu Oct 18 10:43:46 2001 Page 5

NYC-WTC_000088710

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