GCMS analysis comments for sample AD28664, Dec 2001

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Data File C:\HPCHEM\l\DATA\DEC0401\28664.D Vial: 18 Acq On 5 Dec 2001 4:58 am Operator: 209 GALOS Sample gc/ms 11/24 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 Cyclopentanecarboxylic acid, 2 Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T.

29.43 4.75 ug/1 1087560 Chrysene-dl2 33.04

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Cyclopentanecarboxylic acid, 2-amin 129 C6H11NO2 040482-05-1 38 2 Butyl hexadecanoate 312 C20H40O2 000000-00-0 35 3 Cyclobutane, 1, 1-dimethyl-2-octyl- 196 C14H28 062338-30-1 27 4 1~Hexene, 2-methyl-98 C7H14 006094-02-6 27 Abundance Scan 2657 (29.434 min}: 28664.D (-) m/ z 56.00 100.00% 56

5000 43 73 257 —.' — T-r-j-r-r 1 1 1 1

miz-? — 20 40 60 L 80A7,101116112143157171 185199213 , J9. ■ ।.. . m/z 57.00 100 120 140 160 180 200 220 240 260 280 300 29.20 29.40 29.60 29.80 49.43% Abundance #5212:Cyclopentanecarboxylic acid, 2-amino-, trans- 56

5000 TIIm A 29.20 29.40 29.60 29.80 30 m/z 43.05 40.47% 69 82 100 129 1 1 | — mm..... ............ i ■ " ' i ■' miz-2 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 Abundance...... #44549; Butyl hexadecanoate 56 . LWA. 29.20 29.40 29.60 29.80 5000 258 m/z 41.05 39.17% 73 240 312 116129 101 157 171185 214 i n 111'1 TTTTTTTTT)T r ■ ■ ■ i ■ ■ ■ ■ i ■ ■' ■ i " ■ ■ i ■ ■ ■ ■ । ■ • ■ ■ ।. ■ ■■।। । miz-2 20 40 60_ 80 100 120 140 160 180 200 220 240 260 280 300 Abundance #21985: Cyclobutane, 1,1-dimethyl-2-octyl- -IT 56 29.20 29.40 29.60 29.80 m/z 55.00 28.79% 5000

27 1 7 83 97 111 125140 168 196 TT—Tnnr TTTTTTTTTTTTTTTTTTTTTTTI1PTTITTTTT ' 1 i 1 ' m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 29.20 29.40 29.60 29.80

28664.D GCMS1126.M Fri Dec 07 15:53:39 2001 Page 1

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