GCMS calibration table data, May 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\1\DATA\MAY0302\9579.D vial: 9 Acq On 3 May 2002 9:52 pm Operator: Sample GC/MS SCAN 4/24 Inst : 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 10 Hexadecanoic acid Concentration Rank 5

R.T. EstConc Area Relative to ISTD R.T.

27.33 2.57 ug/1 201358 Phenanthrene-dl0 25.58

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 Hexadecanoic acid 256 C16H3202 000057-10-3 95 2 Pentadecanoic acid 242 C15H30O2 001002-84-2 90 3 Tetradecanoic acid 228 C14H28O2 000544-63-8 87 4 Tridecanoic acid 214 C13H2602 _______ 000638-53-9 86 Abundance Scan 2432 (27.327 min): 9579.D (-) m/z 73.10 100.00% 43 60 73

5000 85 — 129 T T 1" I I I ga T r—r [ 1 1 « i |

-1 l'l 97 115 143 157 171 185 199 213 227 w i: ----- T i 1 "" i 14llr I I I II I I I 256 ■ । ■ ■ ■ • । ■ m/ Z 27.00 27.20 27.40 27.60 4 3.05 93.70% m/z--> 40I 60 80 100 120 140 160 180 200 220 240 260 Abundance #35186: Hexadecanoic acid 43 60 73

5000 27.00 27.20 27.40 27.60 85 97 129 m/z 60.00 89.36%

.L 157 171 185 213 256 1 1 1 1 ' 1 1 1 1 1 i 1 I , Il , , 1 1 i 1 ' 1 1 i ■ ' ' 1 i ■ 1 ' 1 i ' ' ‘ r i 1 ' ' 1 i 1 1 ■ ' i ' - | m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 Abundance #71237: Pentadecanoic acid 60 73 I I I I I I I I Illi I I I I I I I I I I I

27.00 27.20 27.40 27.60 5000 m/z 41.05 72.58% 42 129 242 85 97 _ 199 ■ ' I' ' 11 I' ' ' 1 i ' I 1 1 ■ ■ i ■ ■ ■ ■ । । । 171 185 I । ■ ■ ■ ■ । ■ > ■ ■ । ■ i ■ ■ ■ ■ i ■ m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 Abundance #70840: Tetradecanoic acid । । । । । । । । । i । i i i i p 1tT 60 73 27.00 27.20 27.40 27.60 m/z 57.10 64.67%

5000 129 85 185 228 , 97 115 Tll , |l, ,1,1, III , ,1 , , 143 171 I 1 1 1 1 1 1 I ' ' ' I I ' ■ 1 • 1 1 ' 1 i 1 ' 1 1 i 1 ' 1 i ■ "I’’ ‘ 1 i m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 27.00 27.20 27.40 27.60

9579.D GCMS0501.M Mon May 06 10:49:57 2002 Page 10

NYC-WTC_000046263