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GCMS analysis results for sample AE11602, June 2002

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TCLP calibration table document dated May 24, 2002, listing deuterated standards and response factors for GCMS analysis.

NYC-WTC_000013943–000013967

Folder label: “GCMS X 5/24/02 A 5/28/02

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NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed) Data File : C:\HPCHEM\1\DATA\MAY2102\11602.D Vial: 31 Acq On : 22 May 2002 8:06 pm Operator: Sample : EXTRACTS/20 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 24 8:19 2002 Quant Results File: -GCNS0520 . RES Quant Method : C:\HPCHEM\1\METHODS\GCMS0520.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Mon May 20 15:10:30 2002 Response via : Initial Calibration DataAcq Meth : GCMS0520

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-Dichlorobenzene-d4 12.15 152 393369 40.00 ug/1 0.00 10) Naphthalene-d8 15.77 136 1539333 40.00 ug/1 -0.02 17) Acenaphthene-diO 21.08 164 742577 40.00 ug/1 0.00 30) Phenanthrene-diO 25.52 188 953592 40.00 ug/1 -0.02 38) Chrysene-dl2 33.57 240 524849 40.00 ug/1 -0.04 44) Perylene-dl2 37.79 264 330078 40.00 ug/1 -0.02 System Monitoring Compounds 28) TCMX 23.22 209 140968 37.77 ug/L 0.00 Spiked Amount 40.000 Recovery 94.43% Target Compounds Qvalue 2) N-nitrosodimethylamine 0.00 74 0 N.D. 3) bis(2-Chloroethyl)ether 0.00 93 0 N.D. 4) 1,3-Dichlorobenzene 0.00 146 0 N.D. 5) 1,4-Dichlorobenzene 0.00 146 0 N.D. 6) 1,2-Dichlorobenzene 0.00 146 0 N.D. 7) 2,2'-oxybi s(1-Chioropropan 0.00 45 0 N.D. 8) N-Nitrosodi-n-propylamine 0.00 70 0 N.D. d 9) Hexachloroethane 0.00 117 0 N.D. 11) Nitrobenzene 13.35 77 1487 N.D. 12) 1sophorone 0.00 82 0 N.D. 13) bis(2-Chloroethoxy)methane 0.00 93 0 N.D. 14) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 15) Naphthalene 15.83 128 103 N.D. 16) Hexachiorobutadiene 0.00 225 0 N.D. 18) Hexachlorocyclopentadiene 0.00 237 0 N.D. 19) 2-Chloronaphthalene 0.00 162 0 N.D. 20) Dimethylphthalate 0.00 163 0 N.D. 21) 2,6-Dinitrotoluene 0.00 165 0 N.D. d 2 2) Acenaphthylene 0.00 152 0 N.D. 23) Acenaphthene 0.00 153 0 N.D. 24) 2,4-Dinitrotoluene 0.00 165 0 N.D. 25) Diethylphthalate 22.57 149 559 N.D. 26) 4-Chiorophenylphenylether 23.22 204 610 N.D. 27) Fluorene 0.00 166 0 N.D. 29) Azobenzene 0.00 77 0 N.D. 31) N-Nitrosodiphenylamine 23.22 168 397 N.D. 32) 4-Bromophenylphenylether 0.00 248 0 N.D. 33) Hexachlorobenzene 0.00 284 0 N.D. 3 4) Phenanthrene 25.52 178 175 N.D. (#) = qualifier out of range (m) = manual integration 11602.D GCMS0520.M Fri May 24 08:20:23 2002 Page 1

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