GCMS calibration quantitation report, Feb 24 2002

NYC 9/11 Public Portal Document quantltatlon Report (QT Kevlewed) F .“Data File : C:\HPCHEM\l\DATA\FEB2102\REFE.D Vial: 71 7 Acq On : 24 Feb 2002 3:54 pm Operator: Sample : gc/ms scan 2/22 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Feb 25 8:17 2002 Quant Results File: GCMS0208.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Thu Feb 21 16:13:52 2002 Response via : Initial Calibration DataAcq Meth : GCMS0208

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.33 152 231295 20.00 ug/1 -0.03 10) Naphthalene-d8 15.97 136 886787 20.00 ug/1 -0.03 17) Acenaphthene-diO 21.29 164 465933 20.00 ug/1 -0.03 29) Phenanthrene-diO 25.73 188 675200 20.00 ug/1 -0.04 38) Chrysene-dl2 33.80 240 489627 20.00 ug/1 -0.04 44) Perylene-dl2 38.08 264 331271 20.00 ug/1 -0.04

System Monitoring Compounds 37) 2,4-DDD 30.81 235 45806 377 5.86 ug/mL 0.31 Spiked Amount 5.000 Recovery = 117.20%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.95 74 55584 6.01 ug/1 # 73 3) bis(2-Chloroethyl)ether 11.72 93 131090 8.62 ug/1 93 4) 1,3-Dichlorobenzene 12.23 146 97642 5.40 ug/1 99 5) 1,4-Dichlorobenzene 12.37 146 102259 5.54 ug/1 99 6) 1,2-Dichlorobenzene 12.90" 146 100159 5.72 ug/1 100 7) 2,2’-oxybis(1-Chloropropan 13.21 45 192497 8.36 ug/1 98 8) N-Nitroso-di-n-propylamine 13.59 70 91623 8.42 ug/1 88 9) Hexachioroethane 13.74 117 31075 4.21 ug/1 93 11) Nitrobenzene 14.02 77 117999 6.47 ug/1 93 12) 1sophorone 14.66 82 275275 8.94 ug/1 97 13) bis(2-Chloroethoxy)methane 15.34 93 155646 8.11 ug/1 96 14) 1,2,4-Trichlorobenzene 15.85 180 85904 5.66 ug/1 99 15) Naphthalene 16.03 128 326017 6.90 ug/1 98 16) Hexachlorobutadiene 16.57 225 30939 3.41 ug/1 99 18) Hexachlorocyclopentadiene 18.77 237 13066 1.96 ug/1 97 19) 2-Chloronaphthalene 19.54 162 195253 7.03 ug/1 98 20) Dimethylphthalate 20.63 163 264258 8.17 ug/1 99 21) 2,6-Dinitrotoluene 20.84 165 48415 6.60 ug/1 91 2 2) Acenaphthylene 20.81 152 307826 7.67 ug/1 99 2 3) Acenaphthene 21.38 153 212910 7.59 ug/1 98 24) 2,4-Dinitrotoluene 22.01 165 60432 6.51 ug/1 # 84 25) Diethylphthalate 22.76 149 265413 7.89 ug/1 98 26) 4-Chlorophenyl-phenylether 22.92 204 109042 7.53 ug/1 93 27) Fluorene 22.90 166 235344 7.69 ug/1 97 2 8) Azobenzen/ 1,2-Diphenylhyd 23.38 77 252497 7.14 ug/L # 91

(#) = qualifier out of range (m) = manual integration REFE.D GCMS0208.M Wed Mar 13 11:09:13 2002 Page 1

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