GCMS reference standard results, February 2002

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Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\l\DATA\FEB2502\REF.D Vial: 4 Acq On : 25 Feb 2002 1:38 pm Operator : Sample : gc/ms scan 1/25 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Feb 28 9:01 2002 Quant Results File: GCMS0208.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed Feb 27 11:30:15 2002 Response via : Initial Calibration DataAcq Meth : GCMS0208

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.32 152 263843 20.00 ug/1 -0.03 10) Naphthalene-d8 15.95 136 992811 20.00 ug/1 -0.04 17) Acenaphthene-diO 21.27 164 518567 20.00 ug/1 -0.04 29) Phenanthrene-diO 25.71 188 716699 20.00 ug/1 -0.05 38) Chrysene-dl2 33.77 240 443521 20.00 ug/1 -0.07 44) Perylene-dl2 38.05 264 294756 20.00 ug/1 -0.07

System Monitoring Compounds 37) 2,4-DDD 30.79 235 38454 5.14 ug/mL 0.29 Spiked Amount 5.000 Recovery = 102.80%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.94 74 28061 2.66 ug/1 # 69 3) bis(2-Chloroethyl)ether 11.70 93 63902 3.68 ug/1 97 4) 1,3-Dichlorobenzene 12.22 146 46159 2.24 ug/1 97 5) 1,4-Dichlorobenzene 12.36 146 49948m 2.37 ug/1 6) 1,2-Dichlorobenzene 12.88 146 49610 2.48 ug/1 98 7) 2,2'-oxybis(1-Chloropropan 13.19 45 94254 3.59 ug/1 97 8) N-Nitroso-di-n-propylamine 13.58 70 40826 3.29 ug/1 # 86 9) Hexachloroethane 13.73 117 13700 1.63 ug/1 97 11) Nitrobenzene 14.00 77 52467 2.57 ug/1 97 12) 1sophorone 14.65 82 115795 3.36 ug/1 99 13) bis(2-Chloroethoxy)methane 15.32 93 72240 3.36 ug/1 98 14) 1,2,4-Trichlorobenzene 15.84 180 40450 2.38 ug/1 98 15) Naphthalene 16.01 128 156491 2.96 ug/1 99 16) Hexachlorobutadiene 16.56 225 14210 1.40 ug/1 97 18) Hexachlorocyclopentadiene 18.75 237 1761 N.D. 19) 2-Chloronaphthalene 19.53 162 87385 2.83 ug/1 96 20) Dimethylphthalate 20.61 163 121858 3.38 ug/1 99 21) 2,6-Dinitrotoluene 20.82 165 17435 2.14 ug/1 90 22) Acenaphthylene 20.79 152 130643 2.93 ug/1 100 23) Acenaphthene 21.36 153 97744 3.13 ug/1 98 24) 2,4-Dinitrotoluene 21.99 165 20490 1.98 ug/1 # 85 25) Diethylphthalate 22.74 149 115802 3.09 ug/1 96 26) 4-Chlorophenyl-phenylether 22.90 204 49123 3.05 ug/1 90 27) Fluorene 22.88 166 103985 3.05 ug/1 98 28) Azobenzen/ 1,2-Diphenylhyd 23.36 77 103303 2.62 ug/L # 88

(#) = qualifier out of range (m) = manual integration REF.D GCMS0208.M Thu Feb 28 09:04:09 2002 Page 1

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