GCMS calibration results for PAHs, Feb 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\1\DATA\FEB14O2\REF1.D Vial: 24 Acq On : 15 Feb 2002 1:32 am Operator: 209 GALOS Sample : GC/MS SCAN 2/11 Inst : GC/MS 209 Mise \ : Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Feb 1511:452002 iQuant Results File: GCMS0208.RES

Quant Method : C:\HPCHEM\l\METHQDS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed Feb 13 11:43:23 2002 Response via : Initial Calibration DataAcq Meth : GCMS0208

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene- 12.34 152 311422 20.00 ug/1 -0.01 10) Naphthalene-d8 15.99 136 1211097 20.00 ug/1 -0.01 17) Acenaphthene-diO 21.30 164 665286 20.00 ug/1 -0.01 29) Phenanthrene-diO 25.76 188 973879 20.00 ug/1 -0.01 38) Chrysene-dl2 33.83 240 730974 20.00 ug/1 -0.02 44) Perylene-dl2 38.10 264 463433 20.00 ug/1 -0.02

System Monitoring Compounds 37) 2,4-DDD 3 0 .82 235 43789 4.48 ug/mL 0.33 Spiked Amount 5.000 Recovery = 89.60%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.97 74 38793 3.11 ug/1 96 3) bis(2-Chloroethyl)ether 11.74 93 92906 (4.54 ug/1 98 4) 1,3-Dichlorobenzene 12.24 146 80161 3.29 ug/1 98 5) 1,4-Dichlorobenzene 12.39 146 85352 3.44 ug/1 96 6) 1,2-Dichlorobenzene 12.90 146 84690 4.5 9 ug/1 99 7) 2,21-oxybis(1-Chloropropan 13.22 45 .153047 ^4.94 ug/1 97 8) N-Nitroso-di-n-propylamine 13.61 70 \70285 (4.80 ug/1 97 9) Hexachloroethane 13.76 117 25895 2.61 ug/1 93 11) Nitrobenzene 14.03 77 98625 3.96 ug/1 98 12) Isophorone 14.68 82 198327 4 71 ug/1 100 13) bis(2-Chloroethoxy)methane 15.35 93 113197 alke ug/1 , 100 14) 1,2,4-Trichlorobenzene 15.87 180 73373 3.54 ug/1 97 15) Naphthalene 16.04 128 266803 4.14 ug/1 99 16) Hexachlorobutadiene 16.58 225 28940 2.33 ug/1 99 18) Hexachlorocyclopentadiene 18.79 237 2996 0.31 ug/1 97 19) 2-Chloronaphthalene 19.55 162 163723 4.13 ug/1 99 20) Dimethylphthalate 20.64 163 234647 $508 ug/1 99 21) 2,6-Dinitrotoluene 20.85 165 39788 3.80 ug/1 96 22) Acenaphthylene 20.83 152 247177 4.31 ug/1 99 23) Acenaphthene 21.40 153 183419 4.58 ug/1 99 24) 2,4-Dinitrotoluene 22.03 165 50349 3.80 ug/1 # 99 25) Diethylphthalate 22.77 149 241423 V5.03 ug/1 99 26) 4-Chlorophenyl-phenylether 22.93 204 97852 4.73 ug/1 97 27) Fluorene 22.92 166 201211 (4.60) uq/l 97 28) Azobenzen/ 1,2-Diphenylhyd 23.40 77 230921 4.57 ug/L 97

(#) = qualifier out of range (m) = manual integration REFl.D GCMS0208.M Fri Feb 15 11:48:46 2002 Page 1

NYC-WTC_000005849