GCMS calibration table for TCLP analysis, Feb 13, 2002

NYC 9/11 Public Portal Document

. • Quantitation Report (Not Reviewed)

Data File : C:\HPCHEM\1\DATA\FEB1102\REFC.D Vial: 44 Acq On : 13 Feb 2002 58 am Operator: 209 GALOS Sample : GC/MS SCAM 1/14 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY. P Quant Time: Feb 13 6:47 2002 Quant Results File: GCMS0208.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri Feb 08 15:29:22 2002 Response via : Initial Calibration DataAcq Meth : GCMS0208

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Di chiorobenzene-d4 12.34 152 222600 20.00 ug/1 0.00 10) Naphthalene-d8 15.99 136 838349 20.00 ug/1 0.00 17) Acenaphthene-diO 21.30 164 452860 20.00 ug/1 0.00 29) Phenanthrene-diO 25.76 188 657314 20.00 ug/1 0.00 38) Chrysene-dl2 33.83 240 474996 20.00 ug/1 -0.02 44) Perylene-dl2 38.10 264 302042 20.00 ug/1 -0.02

System Monitoring Compounds 37) 2,4-DDD 30.83 235 29050 3.56 ug/mL 0.34 Spiked Amount 5.000 Recovery = 71.20%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.97 74 12281 1.38 ug/1 85 3) bis(2-Chloroethyl)ether 11.74 93 30948 2.12 ug/1 98 4) 1,3-Dichlorobenzene 12.24 146 23257 1.34 ug/1 93 5) 1,4-Diehlorobenzene 12.24 146 23257 1.31 ug/1 92 6) 1,2-Dichlorobenzene 12.91 146 25067 1.49 ug/1 97 7) 2,2'-oxybis(1-Chloropropan 13.23 45 52026 2.35 ug/l 97 8) N-Nitroso-di-n-propylamine 13.61 70 22522 2.15 ug/1 97 9) Hexachloroethane 13.77 117 6147 0.87 ug/1 94 11) Nitrobenzene 14.03 77 29140 (1.69) ug/1 100 12) 1sophorone 14.69 82 64511 (2:22ug/l 99 13) bis(2-Chloroethoxy)methane 15.36 93 38376 .12ug/l 99 14) 1,2,4-Trichlorobenzene 15.88 180 21877 1.52 ug/1 95 15) Naphthalene 16.04 128 86853 1.95 ug/1 98 16) Hexachlorobutadiene 16.59 225 6151 .0.72) ug/1 100 18) Hexachlorocyclopentadiene 18.79 237 618 19) 2-Chloronaphthalene 20) Dimethylphthalate 19.56 20.64 162 163 48065 77133 ug/1 .78) ug/1 96 99 21) 2,6-Dinitrotoluene 20.86 165 8445 .14ug/1 99 22) Acenaphthylene 20.84 152 74561 ug/1 99 2 3) Acenaphthene 21.40 153 57490 .1 ug/1 98 24) 2,4-Dinitrotoluene 22.03 165 9458 1.05 ug/1 92 25) Diethylphthalate 22.77 149 77165 2.36 ug/1 98 26) 4-Chlorophenyl-phenylether 22.94 204 30415 2.16 ug/1 99 27) Fluorene 22.92 166 61937 ug/1 97 28) Azobenzen/ 1,2-Diphenylhyd 23.41 77 70225 ug/L 97

(#) = qualifier out of range (m) = manual integration REFC.D GCMS0208.M Wed Feb 20 12:01:39 2002 Page 1

NYC-WTC_000009554