GCMS calibration table with surrogate recovery data, Feb 24, 2002

NYC 9/11 Public Portal Document

3 ‘ Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\1\DATA\FEB2102\REFD2.D Vial: 59 Acq On : 24 Feb 2002 2:12 am Operator: Sample : gc/ms scan 2/21 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Feb 28 14:59 2002 Quant Results File: GCMS0208.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Thu Feb 21 16:13:52 2002 Response via : Initial Calibration DataAcq Meth : GCMS0208

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.33 152 218382 20.00 ug/1 -0.02 10) Naphthalene-d8 15.97 136 850993 20.00 ug/1 -0.02 17) Acenaphthene-diO 21.29 164 472083 20.00 ug/1 -0.02 29) Phenanthrene-diO 25.73 188 683307m 20.00 ug/1 -0.03 38) Chrysene-dl2 33.80 240 460405 20.00 ug/1 -0.04 44) Perylene-dl2 38.08 264 309195 20.00 ug/1 -0.04

System Monitoring Compounds 37) 2,4-DDD 30.81 235 50599 6. -TO ug/mL. Y) 0.31 Spiked Amount 5.000 Recovery 128.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.95 74 51053 5.84 ug/1 # 76 3) bis(2-Chloroethyl)ether 11.72 93 126805 8.83 ug/1 93 4) 1,3-Dichlorobenzene 12.23 146 65997 3.86 ug/1 100 5) 1,4-Dichlorobenzene 12.37 146 72950 4.19 ug/1 99 6) 1,2-Dichlorobenzene 12.89 146 77491 4.68 ug/1 99 7) 2,2'-oxybis(1-Chloropropan 13.21 45 185013 8.51 ug/1 98 8) N-Nitroso-di-n-propylamine 13.60 70 90165 8.78 ug/1 # 86 9) Hexachloroethane 13.74 117 13977 2.01 ug/1 94 11) Nitrobenzene 14.01 77 114307 6.53 ug/1 98 12) 1sophorone 14.66 82 259280 8.77 ug/1 98 13) bis(2-Chloroethoxy)methane 15.34 93 145459 7.90 ug/1 97 14) 1,2,4-Trichlorobenzene 15.85 180 64435 4.42 ug/1 98 15) Naphthalene 16.03 128 298176 6.58 ug/1 98 16) Hexachlorobutadiene 16.57 225 10686 1.23 ug/1 99 18) Hexachlorocyclopentadiene 18.77 237 3804 0.56 ug/1 # 92 19) 2-Chloronaphthalene 19.54 162 178063 6.33 ug/1 99 20) Dimethylphthalate 20.63 163 258099 7.87 ug/1 99 21) 2,6-Dinitrotoluene 20.84 165 49463 6.66 ug/1 89 22) Acenaphthylene 20.81 152 306995 7.55 ug/1 99 2 3) Acenaphthene 21.38 153 207684 7.31 ug/1 99 24) 2,4-Dinitrotoluene 22.01 165 62406 6.63 ug/1 # 82 25) Diethylphthalate 22.76 149 265328 7.79 ug/1 96 26) 4-Chlorophenyl-phenylether 22.91 204 103037 7.03 ug/1 98 27) Fluorene 22.90 166 227901 7.35 ug/1 99 28) Azobenzen/ 1,2-Diphenylhyd 23.38 77 250202 6.98 ug/L # 90

(#) = qualifier out of range (m) = manual integration REFD2.D GCMS0208.M Thu Feb 28 15:00:41 2002 Page 1

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