DEP GCMS data table, Jan-Feb 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\1\DATA\FEB0802\REFC.D Vial: 43 Acq On : 10 Feb 2002 2:05 am Operator: 209 GALOS Sample : GC/MS SCAN 2/8 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Feb 14 16:10 2002 iQuant Results File: GCMS0208.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed Feb 13 11:43:23 2002 Response via DataAcq Meth : : Initial Calibration GCMS0208 25 )1 Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.34 152 521035 20.00 ug/1 0.00 10) Naphthalene-d8 15.99 136 2010784 20.00 ug/1 0.00 17) Acenaphthene-diO 21.30 164 1081342 20.00 ug/1 0.00 29) Phenanthrene-diO 25.76 188 1591058 20.00 ug/1 0.00 38) Chrysene-dl2 33.83 240 1164596 20.00 ug/1 -0.02 44) Perylene-dl2 38.11 264 789678 20.00 ug/1 0.00

System Monitoring Compounds 37) 2,4-DDD 30.82 235 60349 3.78 ug/mL 0.33 Spiked Amount 5.000 Recovery = 75.60%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.97 74 27316 1.31 ug/1 95 3) bis(2-Chloroethyl)ether 11.74 93 67379 (197/ ug/1 99 4) 1,3-Dichlorobenzene 12.24 146 57055 1.40 ug/1 98 5) 1,4-Dichlorobenzene 12.39 146 62167m . 5 0 ug/1 6) 1,2-Dichlorobenzene 12.90 146 60812 1.54 ug/1 99 7) 2,21 -oxybis(1-Chloropropan 13.23 45 111315 .15-ug/1 98 8) N-Nitroso-di-n-propylamine 13.61 70 51712 1lug/1 95 9) Hexachloroethane 13.76 117 18482 -11ug/1 97 11) Nitrobenzene 14.03 77 69352 -6B<ug/1 95 12) Isophorone 14.68 82 142596 .04/ug/1 100 13) bis(2-Chloroethoxy)methane 15.36 93 83900 -1.93 ug/1 99 14) 1,2,4-Trichlorobenzene 15.88 180 53306 ug/1 99 15) Naphthalene 16.04 128 194067 ug/1 99 16) Hexachlorobutadiene 16.59 225 20631 1.00 ug/1 96 18) Hexachlorocyclopentadiene 18.79 237 3690 19) 2-Chloronaphthalene 19.55 162 118571 NB ug/1 1.84 99 20) Dimethylphthalate 20.64 163 176354 100 21) 2,6-Dinitrotoluene 20.86 165 27686 —1.63—ug/1 97 22) Acenaphthylene 20.83 152 179718 1.93 ug/1 99 23) Acenaphthene 21.40 153 132395 203ug/1 99 24) 2,4-Dinitrotoluene 22.03 165 35852 1—1.66 ug/1 99 25) Diethylphthalate 22.77 149 183324 2, 35 ug/1 99 26) 4-Chlorophenyl-phenylether 22.94 204 72247 (2.15 ug/1 97 27) Fluorene 22.92 166 149279 (2.10ug/1 100 28) Azobenzen/ 1,2-Diphenylhyd 23.40 77 172195 —2.10 ug/L 99

(#) = qualifier out of range (m) = manual integration REFC.D GCMS0208.M Thu Feb 14 16:13:44 2002 Page 1

NYC-WTC_000004161