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GCMS calibration data for TCLP analysis, May 2002

Machine-extracted title · confidence 90%

Calibration table listing response factors for deuterated standards used in TCLP analysis on May 5, 2002.

NYC-WTC_000023148–000023155

Folder label: “GCMS X 5/8/02 A 5/9/02

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NYC 9/11 Public Portal Document

Data File C: \HPCHEM\ 1 \DATA\MAYO 302\9575.D Vial: 48 Acq On 5 May 2002 2:04 pm Operator: Sample GC/MS SCAN 4/23 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L Peak Number 2 Cyclopentasiloxane, decamethyl Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 14.80 2.83 ug/1 237287 Naphthalene-d8 15.82 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Cyclopentasiloxane, decamethyl- 370 C10H3005Si5 000541-02-6 2 3,4-Dihydroxybenzyl alcohol,tris(tr 356 C16H3203Si3 068595-79-9 46 3 Benzoic cid, 2,4-bis[(trimethylsil 370 C16H30O4Si3 010586-16-0 38 4 Benzoic cid, 4-[(trimethylsilyl)ox 282 C13H2203Si2 002078-13-9 37 Abundance Scan 1065 (14.797 min): 9575.D (-) m/z 73.10 100.00%| 73

5000 267 355

45 14.40 14.60 14.80 15.00 15.20 i li 108125 154 177193 223 251 , 323339 li ' i" " 1" " ‘‘‘‘1PumauTmaTTPWTTTTTTTTTTT m/z 267.05 32.58% m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 Abundance #51266: Cyclopentasiloxane, decamethyl- 73

355 267 5000 14.40 14.60 14.80 15.00 15.20 m/z 355.10 32.55% 191207 251 323339 i " "i " i ""i " i " “ i 1’11714/ ।■1 ■। i1' " i “ " i ‘- 'i " mz-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 Abundance #49868:3,4-Dihydroxybenzyl alcohol,tris(trimethylsilyl)- 73 - ' 1 ' 1 1 ' I 1 1 14.40 14.60 14.80 15.00 15.20 5000 267 m/z 356.10 11.54% 179 356 147 209 237 , 312 341 I....... " i' " ■ i " " i " " i " i " " " i ■r'" 11" ' r " ■ ir " i1' ■ ' i ‘ " ■ r ■ " f" 11" " i m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 Abundance #73975: Benzoic acid, 2,4-bis[(trimethylsilyl)oxy]-, trimet 73 14.40 14.60 14.80 15.00 15.20 m/z 268.05 8.93%

5000 355 45

,............... 133149 ..... 193 ? 223.......,281........ 340..... 370 .................................................. m/z—> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 14.40 14.60 14.80 15.00 15.20

9575.D GCMS0501.M Tue May 07 15:01:21 2002 Page 2

NYC-WTC_000023154

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NYC-WTC_000023154Source: NYC Law Department, mirrored locally

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