GCMS calibration data for TCLP analysis, May 2002

NYC 9/11 Public Portal Document

Data File C:\HPCHEM\1\DATA\MAYO302\9574.D Vial: 47 4 Acq On 5 May 2002 1:05 pm Operator: Sample GC/MS SCAN 4/23 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 2 Cyclopentasiloxane, decamethyl Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T.

14.80 3.19 ug/1 290840 Naphthalene-d8 15.82

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Cyclopentasiloxane, decamethyl- 370 C10H3005Si5 000541-02-6 53 2 Benzoic acid, 2,4-bis (trimethylsil 370 C16H30O4Si3 010586-16-0 38 3 Benzeneethanamine, N- (pentafluorop 563 C24H34F5NO3Si3 055429-13-5 38 4 3,4-Dihydroxybenzyl alcohol,tris(tr 356 C16H3203Si3 068595-79-9 37 Abundance Scan 1065 (14.797 min): 9574.D (-) m/ z 73.10 100.00%| 73

5000 267 355 mmm... .. 45 14.40 14.60 14.80 15.00 15.20 108 154 193 223 , 323 - —T I’1 1* 11/ ■ ■ । ' ■ ■ • । 1 ■ ■ ■ । 1 1 ■ ■ । ■ m/z 267.05 34.24% m/z-> 50 100 150 200 250 300 350 400 450 500 550 Abundance #51266: Cyclopentasiloxane, decamethyl- 73

355 267 5000 14.40 14.60 14.80 15.00 15.20 m/Z 355.10 32.84% ■ ■ ■ i ' ' .2 —I ———323 ————————————— m/z-> 50 100 150 200 250 300 350 400 450 500 550 Abundance #73975: Benzoic acid, 2,4-bis[(trimethylsilyl)oxy]-, trimet 73

14.40 14.60 14.80'15.00 15.20 5000 355 m/z 356.10 11.21% 45 133 193 223 281 ————————————————————— mlz-> 50 100 150 200 250 300 350 400 450 500 550 Abundance #74706: Benzeneethanamine, N-[(pentaf)uorophenyl)methylene] 73 355 14.40 14.60 14.80 15.00 15.20 m/z 267.95 8.93% 5000

45 | 208 251 281 , , I 386... 458 548 ‘ 'I ' ’ m/z—> 50 100 150 200 250 300 350 400 450 500 550 14.40 14.60 14.80 15.00 15.20

9574.D GCMS0501.M Tue May 07 15:01:07 2002 Page 2

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