GCMS calibration data for TCLP analysis, May 2002

NYC 9/11 Public Portal Document

Data File C:\HPCHEM\l\DATA\MAY0302\9574.D Vial: 47 Acq On 5 May 2002 1:05 pm Operator: Sample GC/MS SCAN 4/23 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

8.16 11.76 ug/1 843905 1,4-Dichlorobenzene-d4 12.19

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 2-Pentanone, 4-hydroxy-4-methyl - 116 C6H1202 000123-42-2 64 2 Acetone/ 58 C3H60 000067-64-1 9 3 CH2=CH/H2C(O)OCH3 100 C5H802 003724-55-8 9 4 N,N'- rs(2-methyl-2-nitrosopentan-4 258 C12H22N2O4 094514-30-4 9 Abundance Scan 341 (8.163 min): 9574.D (-) m/ z 43.05 100.00% 43

5000 59

1 1 i ' ' ' ' i ■ ■ ■ ' i ■ 1 'T i 1 ■ ' ' i 1 101 7.80 8.00 8.20 8.40 8.60 --AL +PTTITTTHH 53 , 69 111" i" " i ■' " i 83 TTTHT rijm 111 H 11... m/ z 59.10 41.98% m/z-> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105110 Abundance #64274:2-Pentanone, 4-hydroxy-4-methyl- 43

5000 59 7 80 8.00 8.20 8.40 8.60 m/z 58.10 17.30% 27 101 83 ....... . 1411111 i " " i" " i TTT TP m/z—> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105110 Abundance #62322: Acetone 43

7 80 8.00 8.20 8.40 8.60 5000 m/z 101.15 12.93% 58 27 1 m/z—> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105110 Abundance #1448: CH2=CHCH2C(O)OCH3 ■ ■ । ■ ■ ' ■ i ■ ■ ■ ■ i । । । । । 43 7.80 8.00 8.20 8.40 8.60 m/ z 41.05 7.06% 5000

58 i " " i" " i 38 4 tTn-rrT — 72 100 TWTTTTITTPTITTTTTTTT i" " i :—*H9911f9—TTmmRTTu m/z—> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105110 7.80 8.00 8.20 8.40 8.60

9574.D GCMS0501.M Tue May 07 15:01:06 2002 Page 1

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