GCMS calibration table for TCLP analysis, May 2002

NYC 9/11 Public Portal Document

Data File C:\HPCHEM\1\DATA\MAY0 302\9520.D Vial: 21 Acq On 4 May 2002 9:41 am Operator: Sample GC/MS SCAN 4/22 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

8.17 93.62 ug/1 6613800 1,4-Dichlorobenzene-d4 12.19

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2 - Pentanone , 4 - hydroxy- 4 -methyl - 116 C6H1202 000123-42-2 64 2 CH2=CHCH2C(O)OCH3 100 C5H802 003724-55-8 10 3 5-Hexen- 2-one 98 C6H10O 000109-49-9 7 4 Acetone________ 58 C3H60 000067-64-1 7 Abundance Scan 341 (8.167 min): 9520. D (-) m/z 43.05 100.00%! 43

5000 59 -------- 101 7.80 8.00 8.20 8.40 8.60

m/z-> 0- ..................... 10 20 30 37 1 40 50 +53+ 60 69 77 83 ' i ' 1 1 ■ i ' 1 ■ ■ i 70 80 ■ i ■ ' ' 1 i ' 1 ' 1 I ' ■ ■ ' i 1 ‘ 90 | 100 110 120 116 m/z 59.05 42.41% Abundance #64274:2-Pentanone, 4-hydroxy-4-methyl- 43

5000 - 59 7.80 8.00 8.20 8.40 8.60 m/z 58.10 16.40%| 27 । 101

miz-> 10 20 I I 30 T 40 +49 50 I 60 ' I ' ■ ■ ■ i 1 ■ ■ ' i

70 80 83 , I ■ i 1 ■ ■ 1 i ■ ■ 1 ■ i ■ ■ ' ■ i ■ '

90 100 110 120 Abundance #1448: CH2=CHCH2C(O)OCH3 43 ............. 1 .................... 7.80 8 00 8.20 8.40 8.60 5000 m/z 101.15 13.50%|

58 3744 ■ । I 72 100 •I । ■ ■ • ■ । I ■ ■ • i ■ ■ ■ ■ । ■ ■ ■ > | i i । ■ ■ । < । > mfe-> 10 20 30 40 50 60 70 80 90 100 110 120 Abundance #63205:5-Hexen-2-one ......... / 43 7 80 8.00 8.20 8.40 8.60 m/z 41.10 6.85%

5000

55 15 27 83 98 p1.......1........ . TT ■ i ■ ■ ■ 1 11711 1‘‘ TIPmmme m/z—> 10 20 30 40 50 60 70 80 90 100 110 120 7.80 8.00 8.20 8.40 8.60

9520.D GCMS0501.M Tue May 07 09:38:43 2002 Page 1

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