GCMS calibration data for TCLP analysis, May 2002

NYC 9/11 Public Portal Document

Data File C:\HPCHEM\1\DATA\MAY0302\9575.D Vial: 48 Acq On 5 May 2002 2:04 pm Operator: Sample GC/MS SCAN 4/23 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T.

8.16 12.88 ug/1 857909 ■1,4-Dichlorobenzene-d4 12.19 Hit# of 5 Tentative ID MW MolForm CAS# Qual f l 2-Pentanone, 4-hydroxy-4-methyl- 116 C6H1202 000123-42-2 72 2 CH2=CIHCH2C(O)OCH3 100 C5H802, 003724-55-8 9 3 5-Hexen-2-one 98 C6H10O 000109-49-9 7 4 Acetone________ 58 C3H60 000067-64-1 7 Abundance / Scan 341 (8.163 min): 9575.D (-) m/z 43.05 100.00% 43

5000 59

101 7 80 8.00 8.20 8.40 8.60 ....................... 1 '1 1 ' ' I '' 38 ■ +53+ 1 1 ■ 1 ■ i ' ' [ 69 83 , | m/z 59.10 42.53% m/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #64274: 2-Pentanone, 4-hydroxy-4-methyl- 4(3

5000 59 7.80 8.00 8.20 8.40 8.60 m/ z 58.10 16.93%| 101

mfe-> 10 20 27 I I 30 TT +49—+ 50 40 60 PPT 70 80 83 90 +100 110 Abundance #1448: CH2=CHCH2C(O)OCH3 43 7 80 8.00 8.20 8.40 8.60 5000 m/z 101.15 12.94%

miz-> 10 20 30 384 40 .... 50 T60....7072 11111 80 90 100 100 110 Abundance #63205:5-Hexen-2-one ...................................... ............ 43 780 8.00 8.20 8.40 8.60 m/z 41.05 6.969

5000

55 15 27 50 | 83 98 ....... I ........ 1........ 38 ■ > i ■ • > ■ l > ■ ■' > । > > i i । • ■ 1 i ’■■ ■ ■ । ■ ■ - ■ । ■ ■ ■ • । ■'■ ■ ■ । ■ 1 । ■ ■ ■ ■ । ■ —FTPPPPT m/z—> 10 20 30 40 50 60 70 80 90 100 110 7.80 8.00 8.20 8.40 8.60

9575.D GCMS0501.M Tue May 07 15:01:20 2002 Page 1

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