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GCMS calibration data for TCLP analysis, May 2002

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Calibration table listing response factors for deuterated standards used in TCLP analysis on May 5, 2002.

NYC-WTC_000023171–000023178

Folder label: “GCMS X 5/8/02 A 5/9/02

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NYC 9/11 Public Portal Document

Data File C : \HPCHEM\ 1 \DATA\MAYO 3029576.D Vial: 49 Acq On 5 May 2002 3 : 03 pm Operator: Sample GC/MS SCAN 4/23 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 Cyclopentasiloxane, decamethyl Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 14.79 4.06 ug/1 400835 Naphthalene-d8 15.83 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Cyclopentasiloxane, decamethyl- 370 C10H3005Si5 000541-02-6 80 2 Benzoic acid, 2-[(trimethylsilyl)ox 282 C13H2203Si2 003789-85-3 43 3 3,4-Dihydroxybenzyl alcohol,tris(tr 356 C16H3203Si3 068595-79-9 43 4 Benzoi acid, 2,6-bis[(trimethylsil 370 C16H30O4Si3 003782-85-2 40 Abundance Scan 1064 (14.793 min): 9576.D (-) m/ z 73.10 100.00%| 73

5000 267 355 14,40 14.60 14.80 15.00 15.20 45 । |, 89 108 133 154 177 193208223 1’1—I0011001 —111—0—pnmpumuDIIT 251 293 .,, 323339. 1, m/z 267.05 31.88%| miz-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 Abundance #51266: Cyclopentasiloxane, decamethyl- 73

355 267 5000 ... 14.40 14.60 14.80 15.00 15.20 m/Z 355.10 29.25%| 191207 251 |, 323339 "’IT i11 ** i “* ■ i III 1 111 “ 1 ■ i " '' i '■11' r ■ I’T m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 Abundance #72298: Benzoic acid, 2-[(trimethylsilyl)oxy]-, trimethylsi 73 267

14.40 14.60 14.80 15.00 15.20 5000 m/z 356.10 10.39%|

135 47 1 1 ( 1 ’■ 1 _L 175 193209 233249 282 I " "I r " ' i " " I'r " i' " ■ i' " ' i'111111...... 11 " r ' " i11'' i " '' i " " i'1 m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 Abundance #49868:3,4-Dihydroxybenzyl alcohol,tris(trimethylsilyl)- ■ i ■ ■ ■ ■ i ■' 1 1 ' 1 1 1 1 1 73 14.40 14.60 14.80 15.00 15.20 m/z 74.10 8.54% 5000 267 179 356 45 147 ....................... ..... 209237, ' ' I ' ' 1 1 I " ' ' I " " I ‘ ' I " " I ‘ 1 1 ' I ' ' ‘ '1 ' 312 341 ' I " ' ’ T'1 1 !■ | H ? I | I T ! ! | ! ! 1 ' i " ■' i " " i'' I rp-r - mJz-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 14,40 14,60 14.80 15.00 15.20

9576.D GCMS0501.M Tue May 07 15:01:34 2002 Page 2

NYC-WTC_000023177

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NYC-WTC_000023177Source: NYC Law Department, mirrored locally

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