GCMS calibration data for TCLP analysis, May 2002

NYC 9/11 Public Portal Document

Data File C : \HPCHEM\ 1 \DATA\MAYO 302\9576.D Vial: 49 Acq On 5 May 2002 3:03 pm Operator: Sample GC/MS SCAN 4/23 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

8.16 14.05 ug/1 1091470 1,4-Dichlorobenzene-d4 12.19

Hit# of Tentative ID MW MolForm CAS# Qual

1 2-Pentanone, 4-hydroxy-4-methyl- 116 C6H1202 000123-42-2 78 2 CH2=CHCH2C(O)OCH3 100 C5H802 003724-55-8 9 3 Acetone 58 C3H60 000067-64-1 7 4 Butane 58 C4H10 000106-97-8 5 Abundance Scan 340 (8.159 min): 9576.D (-) m/z 43.00 100.00% 43

5000 59

101 7 80 8.00 8.20 8.40 8.60 ....................................... 38. 69 83 | m/z 59.10 42.07% 1 1 i 1 1 1 1 i 1 1 1 1 i 1 1 1 ' r1 ' 1 i ■ ■ ■ 1 t ' ' ' ' i • ■ ' 1 i 1 ' 1 1 i ' m/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #64274:2-Pentanone, 4-hydroxy-4-methyl- 43

5000 1 ■ i ■ ■ ■ 1 । ' 1 । ■ 1 । ■ ■ ' ■ । ■ 59 780 8.00 8.20 8.40 8.60 m/z 58.10 16.68%

m/z-> 27 ........ ''I1..... 10 20 30 40 +4950 + -TT 60 70 80 83 90 + 101

100 110 Abundance #1448: CH2=CHCH2C(O)OCH3 43 7.80 8.00 8.20 8.40 8.60 5000 m/z 101.15 13.22%

58 ............ . 1 72 100 1i ■ ■ ■ ■ i ■ ■ ■ ■ i ‘ ■ 'I1-------------- r । 1" । । . miz-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #94: Acetone 43 7 80 8.00 8.20 8.40 8.60 m/z 41.05 6.99% 5000 15 58 27

/z—> 1 1 1 10I ll, '20I ' ,11,130 ' ' 40rl 1 ■ ■50I ' ' 60 70 80 90 100 110 7.80 8.00 8.20 8.40 8.60

9576.D GCMS0501.M Tue May 07 15:01:33 2002 Page 1

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