GCMS calibration data for TCLP method, May 2002

NYC 9/11 Public Portal Document

Data File C:\HPCHEM\1\DATA\MAY0 302\9571.D Vial: 45 Acq On 5 May 2002 11:08 am Operator: Sample GC/MS SCAN 4/23 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

8.16 12.16 ug/1 892000 1,4-Dichlorobenzene-d4 12.19

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Pentanone, 4-hydroxy-4-methyl- 116 C6H1202 000123-42-2 64 2 3-Hydroxy-2-pentanone 102 C5H10O2 003142-66-3 9 3 CH2=CHCH2C(O)OCH3 100 C5H802 003724-55-8 9 4 5-Hexen-2-one 98 C6H10O 000109-49-9 7 Abundance 1 Scan 341 (8.162 min): 9571 .D (-) m/z 43.05 100.00% 43

5000 59

101 780 8.00 8.20 8.40 8.60 । 1 ■ ■ ■ i ■ ■ ■ ■ । 38L —53 , 69 83 , | m/z 59.10 42.24% m/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #64274:2-Pentanone, 4-hydroxy-4-methyl- 43

5000 59 7.80 8.00 8.20 8.40 8.60 m/z 58.10 16.64%| 27 — 101 miz—> 10 20 I I 30 — 40 +4950—+ 60 I ■ ■ ■ ■ i

70 ■ ■ ' ■ i

80 83 ''' ' ' i

90 ■ ■ ' 1

100 । i ' ■ ■ '

110 i '

Abundance #1691:3-Hydroxy-2-pentanone 31 59

7.80 8.00 8.20 8.40 8.60 5000 m/z 101.15 13.52% 45 15 i . । . . . . . . 1‘ I‘ 66 73 84 102 ■ ■ i ■ ' I ■ ' ■ ■ i r 1 r 1 i ' 1 1 1 I ' ' ' 1 1 1 1 1 1 1 1 miz-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #1448: CH2=CHCH2C(O)OCH3 4)3 7.80 8.00 8.20 8.40 8.60 m/ z 41.05 7.14% 5000

58

n/z-> .............. 10 20 30 40 .50 . I60. 7270 80 I* 90 100 100 110 Ti ttrE—nu । ■ ■ ■ • 1m3a 7.80 8.00 8.20 8.40 8.60

9571.D GCMS0501.M Tue May 07 15:00:39 2002 Page 1

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