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GC/MS calibration data for TCLP method, Oct 2001

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Calibration table and chromatographic data for the TCLP method using GC/MS instrument 209, dated October 4, 2001.

NYC-WTC_000087447–000087457

Folder label: “GC/MS Scan 9/19/01

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\HPCHEM\1\DATA\OCT0101\LBF.D Vial: 6 Acq On : 1 Oct 2001 6:37 pm Operator: 209 GALOS Sample : 9/19 Inst : GC/MS 209 Mise : Multiplr; 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP091101.M (RTE Integrator) Title : 209 625/TCLP calibration table 7/16/01 Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 4 1,4-Dichlorobenzene-d4 Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T. 11.64 0.54 ug/1 73046 1,4-Dichlorobenzene-d4 11.79

Hit# Of 5 T^tative ID MW MolForm CAS# Qual

1 l,4-DichlQZbbenzene-d4 150 C6C12D4 003855-82-1 53 2 Benzene-^^f; 2,3,4-d4-, 5,6-dichloro- 150 C6C12D4 002199-69-1 43 3 Acenaphthylene 152 C12H8 000208-96-8 10 4 Benzaldehyde, 2-hydroxy-5-methoxy- 152 C8H8O3 000672-13-9 9 Abundance Scan 719 (11.643 min); LBF.D (-) m/z 149.90 100.00% liiO (1 5000 115 52 78 87 11.40 11.60 11.80 12.00 44^ m/z 151.90 66767% ■n/z-> Abundance 30 40 50 60 70 80 90 #9593:1.4-Dichlorobenzene-d4 100 110 120 130 140 150 160

1!i0 n - 5000 115 78 11.40 11.60 11.80 12.00 52 m/z 114.90 34.97% 35 ' I' T>/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 “ibundance #9592; Benzene-1,2,3,4-d4-. 5,6-dichloro- 1$0 L 115 11.40 11.60 11.80 12.00 5000 52 78 m/z 78.05 21754%

35 87

Ti/z-> 30 I 40 50 ' I' ' ' ' I ' 60 70 80 I ' I ' ' ' ' I ' 90 100 110 120 A 130 140 150 160 Abundance #67015; Acenaphthylene }\ 152 11.40 11.60 11.80 12.00 m/z52.00 16.77% (1 5000

76 ,ll 87 98 126 ' I ' ' ' ' I ' ' ' ' I ' ' I ' ' ' ' I ' I I ' I ' ' ‘ ' I ‘ ' I ' ' ' ' I ' ' ' ' I ' ' I ' I '' ' ' I ' ■n/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 11.40 11.60 11.80 12.00

LBF.D NP091101.M Wed Oct 03 14:32:46 2001 Page 4

NYC-WTC_000087456

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NYC-WTC_000087456Source: NYC Law Department, mirrored locally

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