GC/MS calibration table for TCLP analytes, October 2001

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\HPCHEM\1\DATA\OCT0101\LBD.D Vial: 4 Acq On : 1 Oct 2001 4:39 pm Operator: 209 GALOS Sample : 9/17 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP091101.M (RTE Integrator) Title : 209 625/TCLP calibration table 7/16/01 Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 7 Butyl hexadecanoate Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T.

29.54 4.05 ug/1 630583 Chrysene-dl2 33.16

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Butyl hexade^ranoate 312 C20H40O2 000000-00-0 32 2 Cyclobutan^ 1,1-dimethyl-2-octyl- 196 C14H28 062338-30-1 27 3 1-Hexene< 2-methyl- 98 C7H14 006094-02-6 27 4 1-Hexyfe, 5-methyl-__________________ 98 C7H14 003524-73-0 27 Abundance Scan 2668 (29.535 min): LBD.D {-) Tm/z 56700 100.00% 53

sigil 4 73 257 ^29 239 I

■n/z-> ' I 20 1 ’P 40 60 < I 143157171185199213

80 100 120 140 160 180 200 220 240 260 280 300 XX ..... . 312 29.20 29.40 29.60 29.80 m/z 56795 47.09% Abundance #44549; Butyl hexadecanoate 5^

5000 258 29.20 29.40 29.60 29.80 240 312 43.05 37.59% 129 m/z I 1°^ I I 157171185 214 ft ' ' ' I ' ' •I I ' ■' r I I . I I I I I I i‘ I . .I I . t I I I |-r I r I I '' ' ‘ I ■n/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 <\bundance #21985: Cyclobutane, 1,1-dimethyl-2-octyl- 5

1^.20 29.40 29.60 29.80 55a m/z 41.00 33.92%

27 70 1 I, I,. 97 111125140 168 196

■n/z~> Abundance 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 #63261:1-Hexene, 2-melhyl- [ yA , A T-r-mr-rT-n-l-ry 5 29.20 29.40 29.60 29.80 m/ Z 73.00 28.08% 41 ft 5000 27 70 I 11''' I'' ’' I'''' I'"' I''" I'''' I'''' I''" I'" ’ I" " I'''' I , , I f , , r-| i-r tJz-> 20 40 60 180 WO 120 140 160 180 200 220 240 260 280 300 29.20 29.40 29,60 29.80

LBD.D NP091101.M Tue Oct 02 12:28:28 2001 Page 7

NYC-WTC_000086993