GCMS calibration table for TCLP analysis, February 2002

NYC 9/11 Public Portal Document

Data File : C: \HPCHEM\1\DATA\FEB1402\1046.D Vial: 9 Acq On : 14 Feb 2002 5:49 pm Operator: 209 GALOS Sample : GC/MS SCAN 1/15 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 1,2-Benzenedicarboxylic acid, Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

34.02 0.30 ug/1 26200 Chrysene-dl2 33.82

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1,2-Benzenedicarbexylic acid, 3-nit 211 C8H5NO6 000603-11-2 78 2 Di-n-octyl (phthalate) 390 C24H3804 000117-84-0 50 3 1,2-Benzenedicarboxylic acid, diiso 390 C24H3804 027554-26-3 49 4 Bis(2-ethylhexyl) phthalate 390 C24H3804 000117-81-7 47 . Scan 3156 (34.019 min): 1046.D(-) ' m/z 149.00 100.00% 149

5000 43 57 167 । 'ii1 83 104 279 33.60 33.80 34.00 34.20 34.40 -------- , , 207 , m/z 167.00 30.06% m/z 20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #25513: 1,2-Benzenedicarboxylic acid, 3-nitro- 149

5000 T"T 33.60 33.80 34.00 34.20 34.40 _ 167 71 m/z 57.00 27.3 9% 1.83 113 132 . • ' l | > ■ ■ • | i • . ■ | ■ > < ' | ■ 1 ■ . | 1 > ■ • | ' ■ ■ ■ | ■ ■ ■ • | ■ 1 | ■ < • ■ | । | '

mz-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance 4l 72 Dl--octyi plithalale.1.. . 1. 149

33.60 33.80 34.00 34.20 34.40 5000 57 m/z 43.05 26.15% 71 167 27 83 113 279 132 20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #53134: 1,2-Benzenedicarboxylic acid, diisooctyl ester 149 i 33.60 33.80 34.00 34.20 34.40 m/z 41.05 2 3.87"% 5000 57 70 167

I | 83 104 279 ----- 1BI A T m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 33.60 33.80 34.00 34.20 34.40

1046.D GCMS0308.M Thu Mar 14 15:30:41 2002 Page 2

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