GCMS calibration table for TCLP analysis, February 2002

NYC 9/11 Public Portal Document

Data File : C:\HPCHEM\1\DATA\FEB1402\1046.D Vial: 9 Acq On : 14 Feb 2002 5:49 pm Operator: 209 GALOS Sample : GC/MS SCAN 1/15 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 Carbon dioxide Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

10.28 0.33 ug/1 27608 1,4-Dichlorobenzene-d4 12.34

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Carbon dioxide 44 CO2 000124-38-9 3 2 Nitrous Oxide 44 N20 010024-97-2 3 3 Acetaldehyde 44 C2H40 000075-07-0 2 4 Ethylene oxide 44 C2H40 000075-21-8 2 Abundance............................ Scan 570 (10.279 min): 1046.D(-) . m/ z 39.95 100.00% 40

44 5000

* ■ । । । ' । r11 t 10.00 10.20 10.40 10.60 36 51 84 I'1" I . ..... I " " i1" ' r " ' i " " r ■ " i ’ ' i'' " r ''' i'1' ■ i' m/ z 43.90 50.58% m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #62263: Carbon dioxide 44

5000 TFTTTTTr Tprrmmpmm 10.00 10.20 10.40 10.60 m/ z 36.00 1.61% 12 16 22 11111111118111164088101111111161000*00801****** m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance 44 1 T -j-T-r 10.00 10.20 10.40 10.60 5000 30 m/ z 51.00 0.87% 14 A " I' " 11" " I' *" I" ’' 11''' I'1" 111111" 111 11′7111 I ■ ■'11'1' ■ I'' " I " 1' I mfe->........... 5.... 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #62264: Acetaldehyde 23 44 10.00 10.20 10.40 10.60 m/ z 45.05 0.66% 5000

m/z-> 1* 5 26 l I" ■' i1 ■' d 111111 ■ ■ ■ i''" i''1' i 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 11'' ■ I l l ■ ■ ■ I ' ■ 10.00 10.20 10.40 10.60

1046.D GCMS0308.M Thu Mar 14 15:30:37 2002 Page 1

NYC-WTC_000052649