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GCMS analysis results for sample AE00307, Jan 2002

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Laboratory report showing GCMS analysis of sample AE00307 for unknown compounds and DDD on January 10, 2002.

NYC-WTC_000051055–000051072

Folder label: “GCMS X 1/7/02 A 1/8/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\MSDCHEM\1\5973N\02JAN08\307.D Vial: 6 Acq On : 8 Jan 2002 9:37 pm Operator: Sample : 508scan Inst : Instrumen Mise 2002 : January 8, Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\l-..\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C : \DATABASE\WILEY7N . L ********************************************************************* Peak Number 9 4-METHOXY-.BETA.-METHYLCINN... Concentration Rank 8

R.T. EstConc Area Relative to ISTD R.T. 22.28 0.13 ug/L 71119 Phenanthrene-dl0 22.63

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 4-METHOXY-.BETA.-METHYLCINNAMIC ... 192 C11H1203 019169-94-9 72 2 3-Cyanocarbazole $$ 9H-Carbazole ... 192 C13H8N2 057102-93-9 59 3 2,4-Diamino-6-(hydroxymethyl)pte... 192 C7H8N60 000945-24-4 59 4 2,4-Diamino-6-(hydroxymethyl)pte... 192 C7H8N60 000945-24-4 53 Abundance Scan 1656 (22.280 min): 307.D (-) m/z 192.10 100.00% 192

5000 , ............ .... 96 146 82 160 22.00 22.20 22.40 22.60

n/z-> 49 0 ■ i ■ ■ ■11111111 —lm ■ ।" 118 11 ‘ ■ ■ ■ ।1 '' ■ ।11 Ti # 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 m/z 96.00 17.78% Abundance #102588: 4-METHOXY-.BETA.-METHYLCINNAMIC ACID $$ 2-Butenoi... 192

108 5000 22.00 22.20 22.40 22.60 146 175 m/z 146.10 17.47%

0 T‘I—B111TTTTT‘rTt1"B‘111TTTTTTII"I"IT"T i ■ ■ ■ ■ । ■ ■ • >। ■ i ■ ■ 111" 11'1 ‘' 11 +TTT ‘111 n/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #103424: 3-Cyanocarbazole $$ 9H-Carbazole-3carbonitrile (CAS 192 — 4 22.00 22.20 22.40 22.60 5000 m/z 191.10 13.51%

n/z-> Abundance Ot ' r ■ " i' m 96 138 164 " I "111" " i1" 11" " i " " i' 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 #102010:2,4-Diamino-6-(hydroxymethyl)pteridine i' " ■ i' " 1 r TTTm

i ' 1 ■ ' i 1 1 192 22.00 22.20 22.40 22.60 163 m/z 193.10 12.43%

5000

66 146 175 34 121 135 .. .......... 0 TIITT ■ i1 " 11" " i'1 "1‘101111100—000TIB‘—PM1—3T0"‘TITT 'll’..... ipe ________________________ I______ I 11 r1'111" 11 I ' 1 1 ' I 1 ' 1 ' 1 ' 1 I m/z~> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.00 22.20 22.40 22.60

307 .D SCAN508.M Wed Jan 09 15:16:57 2002 Page 11

NYC-WTC_000051069

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