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GCMS analysis results for sample AE00276, Jan 2002

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Laboratory report showing GCMS analysis of sample AE00276 for unknown compounds and DDD on January 10, 2002.

NYC-WTC_000051040–000051054

Folder label: “GCMS X 1/7/02 A 1/8/02

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File C:\MSDCHEM\1\5973N\O2JANO8\276.D Vial: 1 Acq On 8 Jan 2002 5:26 pm Operator: Sample 508scan Inst : Instrumen Mise January 8, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L

Peak Number 6 4-METHOXY-.BETA.-METHYLCINN... Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T. 22.28 0.13 ug/L 85354 Phenanthrene-dl0 22.65 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 4-METHOXY-.BETA.-METHYLCINNAMIC ... 192 C11H1203 019169-94-9 72 2 3-Cyanocarbazole $$ 9H-Carbazole... 192 C13H8N2 057102-93-9 59 3 N-perdeuteriobenzylideneaniline 192 C13D11N 000538-51-2 58 4 2,4-Diamino-6-(hydroxymethyl )pte... 192 C7H8N6O 000945-24-4 53 Abundance Scan 1656 (22.280 min): 276.D (-) m/z 192.10 100.00% 192

5000 ...... /......... * 82 96 146 160 . 22.00 22.20 22.40 22.60 66 I /z-> 0 i " 1 ‘ i' "111111111 III 11 r ' i ■'1' i ■ ■' ■ i' ■ ■ ■ i''' ‘ r ' 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 TTT n.. P m/z 146.10 16.30% Abundance #102588: 4-METHOXY-.BETA.-METHYLCINNAMIC ACID $$ 2-Butenoi... 192

5000 108 -----A — 22.00 22.20 22.40 22.60 146 175 m/z 96.10 14.90%

0 " 111" i " 111" " i' ■" I " '' 111' 11' 1111" TTTTTTIITT’II’I IIII+’I’+III’ 11... 111 m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #103424: 3-Cyanocarbazole $$ 9H-Carbazole-3-carbonitrile (CAS 192

22.00 22.20 22.40 22.60 5000 m/z 191.00 13.46%

96 164 138 0 '11'1111" " i11111" " I" " I" " I " mTTT ' r '1' i " " r n/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #88409: N-perdeuteriobenzylideneaniline 192 22.00 22.20 22.40 22.60 m/z 193.10 12.50% n 5000 82

54

0 30 + — HP I ■ ■'' I i ■■ ■■ i I16094 110

m/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 "I'.......... "I''■ ■ 111■ ■ l........................... . u ................... .... .............. ......

22.00 22.20 22.40 22.60

276.D SCANS08.M Wed Jan 09 15:16:16 2002 Page 8

NYC-WTC_000051051

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NYC-WTC_000051051Source: NYC Law Department, mirrored locally

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