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GCMS analysis results for sample AD31585, Jan 28 2002

Machine-extracted title · confidence 100%

Laboratory report showing GCMS analysis of sample AD31585 including unknown compounds and surrogate recovery data.

NYC-WTC_000049902–000049915

Folder label: “GCMS X 1/3/02 A 1/17/02

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NYC 9/11 Public Portal Document Library Search Compound Report

Data File : C:\MSDCHEM\1\5973N\02JAN17\31585.D Vial: I * Acq On : 17 Jan 2002 2:50 pm Operator: Sample : 508 scan Inst : Instrumen Mise : January 17, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 5 3-Cyanocarbazole $$ 9H-Carb... Concentration Rank 4 R.T. EstCono Area Relative to ISTD R.T. 22.28 0.13 ug/L 63179 Phenanthrene-dl0 22.63 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 3-Cyanocarbazole $$ 9H-Carbazole... 192 C13H8N2 057102-93-9 80 2 4-METHOXY-.BETA.-METHYLCINNAMIC ... 192 C11H1203 019169-94-9 72 3 N-perdeuteriobenzylideneaniline 192 C13D11N 000538-51-2 58 4 N-(2-methylprop-2-enyl)-2-nitrob... 192 C10H12N2O2 000000-00-0 46 Abundance Scan 1656 (22.280 min): 31585.D (-) m/z 192.10 100.00% 192

5000

96 ____________ ______________ - • ■ i ■ ■ ■ • i ■ ■ ■ ■ i ■ ■ - ■ i - ■ ■ - 44 70 82 146 -|60 22.00 22.20 22.40 22.60 0- mH 11m90—mnBm0a*mmg’ m/z 96.00 19.94% nz—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #103424:3-Cyanocarbazole $$ 9H-Carbazole-3-carbonitrile (CAS 192

5000 ' 22.00 22.20 22.40 22.60 96 164 m/z 193.10 16.42%

iz—> 0 “‘‘‘1111101771’22111111150101/1173 pmT 138

20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Wt L Abundance #102588: 4-METHOXY-BETA.-METHYLCINNAMIC ACID $$ 2-Butenoi... 192

22.00 22.20 22.40 22.60 108 5000 m/z 191.10 14.85% 146 175

O 117t019111931111T/:292210100100001T1"I"TT 1‘21111111—2771‘T Tp-rrrp-rrrp- 1 ' | ‘ 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #88409: N-perdeuteriobenzylideneaniline ‘I

1512 .... .... n 22.00 22.20 22.40 22.60 m/z 146.10 13.48% 5000- 82

54 110 30 l 94 160 /z-> mlapli.... Of mmm ■ ■ i ■ ■ ‘ ■ i “ ■ ■ 11 j >-r-r> | i > > 1111 ■ 11 > ■ ■ ■ |-i ■ > > । ■ i > j ■ i H1 2030405060 70 8090 100 110 120 130 140 150 160 170 180 190 200 T A I • 1 1 ‘ I 22.00 22.20 22.40 22.60

31585.D SCAN508.M Tue Jan 22 08:36:51 2002 Page 7

NYC-WTC_000049912

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NYC-WTC_000049912Source: NYC Law Department, mirrored locally

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