GCMS calibration results for sample AE09587, May 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File C:\HPCHEM\1\DATA\MAY0302\9587.D Vial: 14 Acq On 4 May 2002 2:47 am Operator: Sample GC/MS SCAN 4/24 FB Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 Cyclopentasiloxane, decamethyl Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 14.80 1.32 ug/1 85574 Naphthalene-d8 15.83 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Cyclopen®! siloxane, decamethyl- 370 C10H3005Si5 000541-02-6 83‘ 2 Benzoic arcid, 2,4-bis[(trimethylsil 370 C16H30O4Si3 010586-16-0 38 3 Phenethylamine, N-methyl-.beta. ,3,4 399 C18H37NO3Si3 G10533-35-S 010538-85-9 38 4 N-(Tripuoroacetyl)-N,O,O',O'1-tetr 553 C22H42F3NO4Si4 000000-00-0 38 Abundance Scan 1065 (14.796 min): 9587.D (-) m/z 73.10 100.00% 73

5000 267 355 ............ J \............................ 45 14.40 14.60 14.80 15.00 15.20 I, 108125 154170 191207223 323339 L____ " i ■ ■ I'1111" " I I" " I ’ '' I i1111 | 11' 111 i11111 m/z 267.05 32.84% m/z-> 40 6080 100 120 140 160 180 200 220 240 260 280 300 320 340 360 Abundance #51266: Cyclopentasiloxane, decamethyl- 73

355 267 — 5000 14.40 14.60 14.80 15.00 15.20 m/z 355.10 30.44%| 191207 251 323339 J ......... ' ■■l|ll TT-p- Ji 1 1 1 1 i 1 1 1 1 । * 1 1 1 । 1 1 1 1 । > 1 * ■ । 1 1 1 । । 1 1 1 । । 1 1 ' 1 । I' " 11 I 1 11 1 I m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 Abundance #73975: Benzoic acid, 2,4-bis[(trimethylsilyl)oxy]-, trimet 73 । । । । । । । । । i / । \ i । । ] । । । । । i r

14.40 14.60 14.80 15.00 15.20 5000 355 m/z 356.10 10.58%| 45

193 i' । 223 281 133149 I । | । i r i | i i i i [ i i i i [ 1 i i i । i ri i । i i i i । > i i r । i i r i । i। | 't r i i | n Mr 1,379 m/z-> Abundance 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 #74239: Phenethylamine, N-methyl-.beta.,3,4-tris(trimethyls 73 TI L nn 14.40 14.60 14.80 15.00 15.20 i 1 1 ' ' i 1 ■

m/z 267.95 8.55%| 5000 355 44

iii , 88 130147 193 267 294 .... ....... .................. I \.................... ‘' ir 1" i ■ ■ r | । 1 1 । I i ■ 1 1 I ■ l’i ' | ' I i1 " ' l | | | 1 1 | 1 1 ''' | r1111"111 ■ । ■ ■ ■ ■ ( ■ ■ ■ ■ । । । । । । । i । ' 1 m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 14.40 14.60 14.80 15.00 15.20

9587.D GCMS0501.M Mon May 06 10:51:12 2002 Page 2

NYC-WTC_000046338