GCMS calibration results for sample AE09587, May 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\1\DATA\MAY0302\9587.D Vial: 14 Acq On 4 May 2002 2:47 am Operator: Sample GC/MS SCAN 4/24 FB Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L Peak Number 1 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T. 8.16 19.26 ug/1 994635 1,4-Dichlorobenzene-d4 12.19

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 2 -Pentanone, 4-hydroxy-4-methyl- 116 C6H1202 000123-42-2 64 2 CH2=CHCH2C(O)OCH3 100 C5H802 003724-55-8 10 3 Acetone/ 58 C3H60 000067-64-1 7 4 2,3-Bunanedione, monooxime______ 101 C4H7NO2 000057-71-6 5 Abundance ' Scan 341 (8.161 min): 9587.D (-) m/z 43.05 100.00% 43

5000 59 - 101 7 80 8.00 8.20 8.40 8.60 ...................................... 38 I i ■ । । । 53.,.) 69 83 , | 3 F | I I kill 1 I I | f I I“ I I “ [ I। ■।'I'i । । । i । । ' । ।—। । । 1 i i-i । । I । i । i । । r m/z 59.10 41.88% m/z-> Abundance 10 20 30 40 50 60 70 #64274: 2-Pentanone, 4-hydroxy-4-methyl- 80 90 100 110 I 43

5000 ............................................. ' 1 i 1 ' ‘ 1 1 1 ■ ' 1 i 1 I ■ 1 ' 1 i 1 , 59 7 80 8.00 8.20 8.40 8.60 m/z 58.10 16.48% 27 101

m/z-> - ' 1 I1" " I I 10 20 30 40 +49+ 60 50 70 80 I । ■ ■ ■ । । । ■ ■ i 83 ■' ■ ■ ■

90 i ■ - 100 110 Abundance #1448: CH2=CHCH2C(O)OCH3 43 , - 7.80 8.00 8.20 8.40 8.60 5000 m/z 101.15 13 .35%

58

m/z-> ........ 38 10 । 1 1 ■ 1 । ■ ’ ■ * । 20 30 ' 1 I 40 .a| 1 72 80 50 60 70 • I ■ ■ ■ ■ । । । । ■ I > । । । । ' 90 100 100 110 Abundance #94: Acetone 1 —............ 43 7 80 8.00 8.20 8.40 8.60 m/z 41.05 6.83%

5000- 15 58 27 , , , .|............. Il,................ । .1 ‘ 1 i 1 1 i 1 11 1 i1 11 1 i 1 T-r-pr-r I I I I I I I < I I I I I I ■ I I I I I I I I I I I I Irav 1 | , mmt T m/z-> 10 20 30 40 50 60 70 80 90 100 110 7.80 8.00 8.20 8.40 8.60

9587.D GCMS0501.M Mon May 06 10:51:11 2002 Page 1

NYC-WTC_000046337