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GCMS sample analysis results for AE10606, May 10 2002

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Laboratory report detailing GC/MS analysis of sample AE10606 including surrogate recovery data in May 2002.

NYC-WTC_000045624–000045642

Folder label: “GCMS X 5/3/02 A 5/7/02

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File C:\MSDCHEM\1\DATA\050702\10606.D Vial : 11 Acq On 7 May 2002 9:17 pm Operator: Mclean Sample 5/3 kb Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 7 Phenanthrene, 9-methyl- Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T. 22.58 0.33 ug/L 383782 Phenanthranene-dl0 22.96 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 50 2 2-Propenal, 3-(3,4-dimethoxyphen.. . 192 C11H1203 004497-40-9 42 3 Anthracene, 2-methyl- 192 C15H12 000613-12-7 40 4 Phenanthrene, 3-methyl-_____________ 192 C15H12 0 0 0 832-71-3/ 40 Abundance Scan 3319 (22.580 min): 10606.D (-3312) (-) m/z 192.10 100/00% 192 A 5000

82 96 146 160 ...... H.... / 22.20 22.40 22.60 22.80 23.00 42 70 । J 118 n/z-> + I | l i l । | > > । । | ' I । I I [ I I I I | । I I । | । * I I | I H I | I I r> | I ! ! । | I ! I I | I I I I | > I ! I |

20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 1 ''111" r " 1111" I m/z 191.10 19.53% Abundance #81033: Phenanthrene, 9-methyl- 192

5000 22.20 22.40 22.60 22.80 23.00 m/z 146.10 15.62% 96 165

n/z—> 29 39 51 63 74 83 j '' I ' ' ' 1 1 1 1 1 1 I I I I I I I I I I I l'l > ' I ■ 1'1 I trTT I I I 1 1

20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 115 126 139 152 > > I i | > I I | | । | i'| i ' i r |I I l i | 111 j 176 Mll— Abundance #80953: 2-Propenal, 3-(3,4-dimethoxyphenyl)- 192 161 1 - 40191 22.20 22.40 22.60 22.80 23.00 5000 m/z 193.00 14.48%

77 91 177 52 . 121 149 ........ . 103 । 138 | 111' ■1 r ' I I I I I I I r I > > I I I I I I 1 I I I I I I I I I I I I I I I I I.. I.. । | I I I I I I I I I I I I I I I TIT m/z-> 20 30 40 50 60 70 80 90 100 110 1 20 130 140 150 160 170 180 190 200 Abundance #125844: Anthracene, 2-methyl- TI ' 1 I ' ' 1 '■ I 1 192 22.20 22.40 22.60 22.80 23.00 m/z 96.00 12.44%

5000

22 96 165 63 74 u l ‘T:‘‘‘$!710110m911110101II 115 139 150 . 176 —T—T—ET0TIuTmEt0uf 1’1’3 ' 1 ' ' ' ' 1 ' ' ' ' ' ' I ' ' ' ' 1 1 m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.20 22.40 22.60 22.80 23.00

10606.D 050102.M Thu May 09 09:12:07 2002 Page 10

NYC-WTC_000045638

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NYC-WTC_000045638Source: NYC Law Department, mirrored locally

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