GC/MS calibration results, PAH compounds, May 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\l\DATA\MAY0202\9451.D Vial: 10 Acq On 2 May 2002 11:38 pm Operator: Sample GC/MS SCAN 4/19 Inst : 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L Peak Number 3 3-Hydroxy-3-methyl-2-butanone Concentration Rank 9

R.T. EstConc Area Relative to ISTD R.T.

7.23 1.47 ug/1 132550 1,4-Dichlorobenzene-d4 12.20

Hit# Of 5, Tentative ID MW MolForm CAS# Qual ____________ /_ 7 1 3-Hydroxy-3-methyl-2-butanone 102 C5H10O2 000115-22-0 38 2 4-Pentene-2-ol, 2-methyl 100 C6H120 000624-97-5 36 3 Acetamide 59 C2H5NO 000060-35-5 9 43-Pencanol 88 C5H120 000584-02-1 9 Abundance Scan 239 (7.233 min): 9451 .D (-) m/z 59.10 100.00% 59

5000 43

। 7 I i I । T i i I s I I I I | । । I , T 1 T 107 6.80 7.00 7.20 7.40 7.60 । 1 1 1 1 । 1 1 1 1 । 1 1 381—458—+ 69 — 7 1, , m/z 43.05 45.55% m/z--> 10 20 30 40 50 60 70 80 90 100 110 Abundance #1697: 3-Hydroxy-3-methyl-2-butanone 59

—..... - 5000 43 | I I 1 1 | I I I I || I I I | [| T1 | II I

6.80 7.00 7.20 7.40 7.60 31 m/z 41.05 17.01% .......... ,........... 69.................87................................ m/z—> ......... 10 20 1111/38,11, 30 40 ' I ’ ' 1 1 I ' 1 1 1 I ' ' 1 1 I ' 50 60 70 80 11 I ' ‘ ' 1 1 1 1 1 1 1 1 1 90 100 110 Abundance #1529: 4-Pentene-2-ol, 2-methyl 59

6.80 7.00 7.20 7.40 7.60 43 5000 m/z 107.05 11.18%

31 11 1 ' 1 .... ’ 1 i5 1 53, 67 85 FTI"rrTru TT 1 1 1 1 1 I ' 1 1'' I 1 1 1 ' i ' ' 1 1 l 1 1 ' ' I ' 1 ' 1 i ‘ ' m/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #62337: Acetamide 59 6.80 7.00 7.20 7.40 7.60 44 m/z 69.05 5.53% ft 5000

m/z--> 15

...... 31 i 1 ' 1 1 i ■ 10 20 ■ ■ ■ i ■ 1 ' ■ i ' 30 40 50 60 70 80 90 100 110 6.80 7.00 . u. | 7.20 7.40 7.60

9451.D GCMS0501.M Fri May 03 08:42:15 2002 Page 3

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