GC/MS analysis results, sample AE09684, May 2002

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Library Search Compound Report

Data File C:\MSDCHEM\1\DATA\020507\09684 .D Vial: 10 Acq On 7 May 2002 9:01 pm Operator: Nefliu Sample sample Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: rteint.e Quant Method : C:\MSDCHEM\1\METHODS\SCAN020507.M (RTE Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1

Peak Number 3 1,2-Phenylene diisothiocyanate Concentration Rank 3 R.T. EstConc Area Relative to ISTD R.T.

31.09 0.36 ug/1 41357 Phenanthrene-dl0 31.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1,2 - Phenylene diisothiocyanate 192 C8H4N2S2 071105-17-4 52 2 Thiophene, 2-[2-(3-thienyl) ethen. . . 192 C10H8S2 116854-09-2 47 3 1,5-Naphthalenedithiole 192 C10H8S2 1000223-69-5 45 4 Bitosc anate 192 C8H4N2S2 004044-65-9 40 Abundance Scan 4767 (31.088 min): 09684.D (-4752) (-) m/z 192.10 100.00% 192

5000

9 96 146 4 cn । 30.80 31.00 31.20 31.40 42 111" " i'1" i"111" " i11 i 70 82106120.... 1160 _... । "p |iiii|iirrpTi I[t 111 । 11 111 11 11 । 11 11 111 r i । >■ Ti 111 ■ । | h 11 ] 11 11 1111 r |' m/z 191.10 19.84% /z—> 0 10 20 30 40 50 60 70 80 90100110120130140150160170180190200 Abundance #80862:1,2-Phenylene diisothiocyanate 192

5000 64 ......... 1 ..........A ■11' ■ ■1111 141111111" 30.80 31.00 31.20 31.40 90 134 m/z 96.00 13.41% 39 75 4 82+++H4 _ I 107 122 , 148 160 'i |l l «T ’ll r‘r4 11 irt ri 11 1 TTTTT " I"1 m/z-> 0 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200 Abundance #81023: Thiophene, 2-[2-(3-thienyl)ethenyl]- 1 12 1 1 I 1 1 ' 1 I 1 1 ■ ■ i ' 1

147 30.80 31.00 31.20 31.40 5000 m/z 146.20 13.41% 45

27 5869 82 9 115 134 , 158 177 VIUuT TTTTTTTT m---- + i'i1 I— m/z-> Abundance 0 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200 #80950:1,5-Naphthalenedithiole 192 1 ■ ' 1 1 > 1 1 I ' ' 30.80 31.00 31.20 31.40 m/z 160.10 9.75% 5000 115 128 159 147 40 57 69 79 96 111111111111 i‘i । i । n ’ । m ytrmn th |*l*i vjd hp ri mm177 1...... /z—> 7 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200 ' ' 1 1 1 ' ' 1 1 1 30.80 31.00 31.20 31.40

09684.D SCAN020507.M Tue May 14 08:40:41 2002 Page 5

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