GC/MS calibration table, sample AE08837, April 2002

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Data File : C:\HPCHEM\1\DATA\APR23O2\8837 .D Vial: 6 Acq On : 23 Apr 2002 7:18 pm Operator: Sample : gc/ms scan 4/15 Inst : 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title 209 625/TCLP calibration table Library C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 7 Butanamide Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T.

9.15 7.58 ug/1 1087090 1,4-Dichlorobenzene-d4 12.22

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 Butanamide 87 C4H9NO 000541-35-5 72 2 3-Hexanol, 3-ethyl- 130 C8H180 000597-76-2 39 3 2-Hexanone, 3-hydroxy-3,5-dimethyl- 144 C8H1602 006321-14-8 39 4 Propan l-ethoxy­ 88 C5H120 000628-32-0 38 Abundance , Scan 447 (9.149 min): 8837.D (-) m/ z 59.05 100.00% 59

5000 43 TT .... 36,1 , 51 69 151 8.80 9.00 9.20 9.40 80 87 95 107 138.. li mz-> 20 ■ I ' 1 ’ ■ i ■ ' '1111' 1 I ■ 30 40 50 1'1 60 70 ■i■ ' 1 ' i ' ' 1 ' i ‘ ■i■1 11 i 1 1 1 ‘ i 1 1 1 1 i'■■1i 11 '1 i ■ 80 90 100 110 120 130 140 150 160 m/ Z 43.00 40.27% Abundance #62880: Butanamide 44 59

.................. ) ............... : 5000 I I I I I I r I I I I I I I I I J II I I I |1

8.80 9.00 9.20 9.40 27 72 m/z 41.00 17.16% 4 | I I I ! [ I I I | । il. 87 > । ■ ■ > ■ | ■ ■ ■ ■ 11' ■ ■ ■ i ■ ■ ■ ■r । ■ ■ ■ ■ । ■ ■ ■ ■ । 11 ■ ■ ■ ■ । ■ 1111 ■ 11111111 mfe-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #65274: 3-Hexanol, 3-ethyl- 59 ■ 1 i 1 1 1 ■ i 1 1 ■ 1 । ' 1 1 ' i ‘ 1 1 ' i ■ 880 9.00 9.20 9.40 5000 m/z 150.90 8.43% 31 70 83 101 45 m/z-> — L t— I I 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 t i | i i > i "J-i ~i—i”T'I" i i i i | i ' i i | i ■< i । i i i i । i ■ i i [ i i t i । i

Abundance #8436: 2-Hexanone, 3-hydroxy-3,5-dimethyl- ”1 i | I - i i | i 1 r i । । )। i । i i i i [ f

59 8.80 9.00 9.20 9.40 m/z 152.90 7.40% 5000 43 101 ................. |....... 69 83 I 111 1 I | I > I I | > I 4 I | I I I ! | I I I I—|[ । । । o CI’l t n । i i । । । । । ‘ I I II II I ' I I I ] I I II I I I I I ‘I"I"UNT"TII‘l I I I l“l I I I I I I I ■ m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 8.80 9.00 9.20 9.40

8837.D GCMS0412.M Wed Apr 24 08:36:40 2002 Page 7

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