GC/MS calibration table, sample AE08837, April 2002

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Data File : C : \HPCHEM\ 1 \DATA\APR2 302\8837.D Vial: 6 Acq On : 23 Apr 2002 7:18 pm Operator: Sample : gc/ms scan 4/15 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Library- : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 8 Butane, 1,3-dichloro-3-methyl- Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

9.66 2.51 ug/1 359581 1,4-Dichlorobenzene-d4 12.22

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Butane, 1 ,/3-dichloro-3-methyl- 140 C5H10C12 000624-96-4 36 2 1-Pentene/, 3-bromo-4-methyl- 162 C6HllBr 000815-47-4 27 3 3-Butyn-2-ol , 2 -methyl - 84 C5H80 000115-19-5 25 4 Butane, G,3-dichloro-2-methyl- 140 C5H10C12 000507-45-9 22 Abundance Scan 503 (9.663 min): 8837.D (-) m/z 41.05 100.00% 41 69 105

77 5000 ...... ...... 53 151 9.40 9.60 9.80 10.00 I-1 I I I I-1 I I I‘l‘ +l,61 89 + IL 171 1 I il I I I | r i i I | n I I | I I I i | i ■ I I | I I I ) m/z 104.95 89.64% m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #7246: Butane, 1,3-dichloro-3-methyl- 69 41 77 /। । । । । r 5000 1 i । i i । । । 1 ' ' 1 1 1 ' 27 9.40 9.60 9.80 10.00 53 105 89 "Z 69.00 86.84% । j i । i r i i n । i lii । । i i i । । ■ । i । i i i । । । < । । । । । ■ । । i i i i । i i ( i p T| i 1 T i' "Tl ’ I' i । i i r । d i | n rt i T m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #12782:1-Pentene, 3-bromo-4-methyl- 41 69 1 1 i ' ' ' ■ 1 1 ' 1 9.40 9.60 9.80 10.00 5000 m/ Z 77.05 52.63%

27 53 148 ■ । ■ ■ । ■ । ■ ■ ■ 11 +HP 106 i111 ■ i11111 । i i i i । i i i I । i re । । i r [ । ii-1 ।

rn/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #580: 3-Butyn-2-ol, 2-methyl- / ' ' ' ' 1 1 1 1 1 1 r 1 1 ' r 1 1 1 1 1 1 ' 1 69 9.40 9.60 9.80 10.00 m/z 107.00 32.34% 43 5000-

27 53 83 ' m , Jl 11 -7L-PPP i111' i ‘11' r 1111 i1 111111 ■ ■ i .... .. ,, | -- 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 9,40 9.60 9.80 10.00

8837.D GCMS0412.M Wed Apr 24 08:36:42 2002 Page 8

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