GCMS method 508 scan data for WTC samples, March 2002

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Library Search Compound Report

Data File : C:\MSDCHEM\1\DATA\031902\3800.D Vial: 10 Acq On : 19 Mar 2002 7:02 pm Operator: McLean Sample : RE-INJ 2/20 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\l\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 14 Iron, monocarbonyl-(1,3-but... Concentration Rank 10

R.T. EstConc Area Relative to ISTD R.T.

33.91 1.52 ug/L 408180 Perylene-dl2 34.18

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Iron, monocarbonyl-(1,3-butadien... 438 C21H22FeN2O5 109007-87-6 78 2 TETRACOSAMETHYLCYCLODODECASILOXA. . . 888 C24H72O12Sil2 018919-94-3 49 3 lH-Purin-6-amine, [ (2-fluorophen.. . 243 C12H10FN5 074421-44-6 38 4 3,6-Dioxa-2,4,5,7-tetrasilaoctan... 294 C10H3002Si4 004342-25-0 38 Abundance Scan 3399 (33.906 min): 3800.D (-) m/z 73.10 100.00% 73

147 221 5000

281 355 PPPPP । > TTTT 429 33.60 33.80 34.00 34.20

m/z-> 0- T TTTTT 0 ult ‘ d‘T 50 100 150 200 250 300 350 400 450 500 550 600 650 700 p-rr-rprm-f m/z 147.10 63.28%

Abundance #350342: Iron, monocarbonyl-(1,3-butadiene-1,4-dicarbonic ... 73

147 221 / 5000 355 4II 113 T 33.60 33.80 34.00 34.20 281 429 m/z 221.10 53.10% 26 503

rn/z-> 0 0 llund m— . La 41 ।, n *■ 577, ■, 652 50 100 150 200 250 300 350 400 450 500 550 600 650 700 • i' ■ ■

Abundance#391010: TETRACOSAMETHYLCYCLODODECASILOXANE $$ Cyclodo 73 355 . —A — 33.60 33.80 34.00 34.20 147 221 281 m/z 281.10 28.85% 5000

415

miz-> 0 ITumi np tr — hr + ....11...।ri 111 ill < j. 0 50 100 150 200 250 300 350 400 450 500 550 600 650 700 Abundance #177443:1H-Purin-6-amine, [(2-fluorophenyl)methyl]- (CAS) N* r MM ............ r 73 1111111 • ■111 33.60 33.80 34.00 34.20 m/z 355.10 25.57%

28 147 221 5000 355 281 429 503 —

miz—> O' pl0 L50L he 4 +Lu 4T | T 563607 653 703 100 150 200 250 300 350 400 450 500 550 600 650 700 1 11 " 33.60 33.80 34.00 34.20 ‘ I

3800.D 5080302.M Thu Mar 21 11:42:35 2002 Page 16 NYC-WTC_000037902