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GCMS method 508 scan data for WTC samples, March 2002

Machine-extracted title · confidence 90%

Instrument data file containing chromatographic scans and compound identification for environmental samples analyzed in March 2002.

NYC-WTC_000037884–000037905

Folder label: “GCMS X 2/20/02 A 3/20/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\MSDCHEM\1\DATA\031902\3800.D Vial: 10 Acq On : 19 Mar 2002 7:02 pm Operator: McLean Sample : RE-INJ 2/20 Inst : Instrumen Mise Multipir: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 13 Iron, monocarbonyl-(1,3-but... Concentration Rank 9 R.T. EstConc Area Relative to ISTD R.T.

31.59 1.84 ug/L 984593 Chrysene-dl2 30.30

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Iron, monocarbonyl-(1,3-butadien... 438 C21H22FeN2O5 109007-87-6 45 2 SILICONE POLYMER 458 C14H42O5Si6 000000-00-0 43 3 BISTRIMETHYLSILYL N-ACETYL EICOS... 511 C28H57NO3Si2 000000-00-0 38 4 1,1,1,5,7,7,7-Heptamethyl-3,3-bi... 444 C13H40O5Si6 038147-00-1 38 Abundance Scan 3144 (31.593 min): 3800.D (-) m/z 73.10 100.00% 73

147 5000 221

281 355 . r- .4 , ----- r t | 429 31.20 31*40 31.60 31.80 32.00

m/z-> 0- - n+—+ —— 50 100 150 200 250 300 350 400 450 500 550 600 650 m/z 147.10 52.17%

Abundance #350342: Iron, monocarbonyl-(1,3-butadiene-1 ,4-dicarbonic ... 73

147 221 5000 355 Tf i ■ ■ • ■ i TTT 31.20 31.40 31.60 31.80 32.00 281 429 m/z 221.10 46.96% 26 111 503

■n/z-> 0- -ulaanu HU -3— — 1 — ,11 — 11T — ■ —577■ I ■»।' I — 652■' 50 100 150 200 250 300 350 400 450 500 550 600 650 Abundance #392084: SILICONE POLYMER 73

i ■ • ■ ‘ i ■ ■ ■' i T uur 31.20 31.40 31.60 31.80 32.00 m/z 281.00 24.72% 5000 147

221 109 281 0J T*4.4192. *P TCT010011111 ■p-r m/z-> 50 100 150 200 250 300 350 400 450 500 550 600 650 Abundance#370710: BISTRIMETHYLSILYL N-ACETYL EICOSASPH1NGA-4,11-Dlt: 73 I M ■ —Ar ' TITPArr 31.20 31.40 31.60 31.80 32.00 m/z 355.10 22.35%

5000 174 129 337 221 281 , 429 — miz—> 0- -- L90 - — 50 100 150 200 250 300 350 400 450 500 550 600 650 y T / I 111111r 31.20 31.40 31.60 31.80 32.00

3800.D 5080302.M Thu Mar 21 11:42:33 2002 Page 15 NYC-WTC_000037901

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NYC-WTC_000037901Source: NYC Law Department, mirrored locally

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