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GCMS analysis report for sample AE02335, March 2002

Machine-extracted title · confidence 100%

Laboratory analysis report for sample AE02335 conducted on March 22, 2002, listing unknown compounds and surrogates.

NYC-WTC_000010537–000010557

Folder label: “GCMS X 1/31/02 A 3/4/02

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NYC 9/11 Public Portal Document Library Search Compound Report

Data File C:\MSDCHEM\l\DATA\030402\2335.D Vial: 7 ‘ ‘ Acq On 4 Mar 2002 3:11 pm Operator: McLean Sample 1/31 Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Library : C:\DATABASE\WILEY7N.L

Peak Number 10 Iron, monocarbonyl-(1,3-but... Concentration Rank 9

R.T. EstConc Area Relative to ISTD R.T.

28.99 0.82 ug/L 418237 Chrysene-dl2 30.34

Hit# of 5 Tentative ID MW MolForm CAS# Qual

l Iron, monocarbonyl-(1,3-butadien— 438 C21H22FeN2O5 109007-87-6 46 2 SILICONE POLYMER 458 C14H42O5S16 000000-00-0 43 3 1,1,1,5,7,7,7-Heptamethyl-3,3-bi... 444 C13H40O5S16 038147-00-1 40 4 Trisiloxane, 1,1,1,5,5,5-hexamet... 384 C12H3604Si5 003555-47-3 38 Abundance Scan 2857 (28.990 mln): 2335.D (-) m/z 73.10 100.00% 73

5000 147 221 281 355 429 28.60 28:80 29.00 29.20 29.40

•n/z-> 01 ...l . r ... L - 50 100 150 200 250 300 350 400 450 500 550 600 650 m/z 147.10 42.33%

Abundance #350342: Iron, monocarbonyl-(1,3-butadiene-1,4-dicarbonic... 73

147 221 5000 ... ... 355 281 28.60 28.80 29.00 29'20 29.40 429 m/z 221.10 30.73% 26 111 503 1 0- 4444 . .577 183 —4,317441,, 44 t . 044418344 Mulluak m ,, 652 94 Tl/z-> 50 100 150 200 250 300 350 400 450 500 550 600 650 Abundance #392084: SILICONE POLYMER 73

. . h. 28.60 28.80 29.00 29.20 29.40 5000 147 m/z 281.00 19.32%

221 109 281 82 * 0- . .. ’1 "Ttinim ., i t 1 r.. J n r. । .. .. ।.... । < 1 1. ।. <. 1 j i 1111 11 11 | 11 1111 r miz-> 50 100 150 200 250 300 350 400 450 500 550 600 650 Abundance #352530:1,1,1,5,7,7,7-Heptamethyl-3,3-bis(trimethylsiloxy... 73 11 ■ ‘ • i ■ ■ TTTm I n n 111 28.60 28.80 29.00 29.20 29.40 m/z 355.00 15.72% 147 5000 267 355 429 207

•n/z-> 50 100 150 200 250 300 350 400 450 500 550 600 650 28.60 28.80 29.00 29.20 29.40

2335.D 5080302.M Mon Mar 18 08:31:30 2002 Page 12

NYC-WTC_000010553

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NYC-WTC_000010553Source: NYC Law Department, mirrored locally

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