GCMS analysis report for sample AE02335, March 2002

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Data File : C:\MSDCHEM\1\DATA\030402\2335.D Vial: 7 Acq On : 4 Mar 2002 3:11 pm Operator: McLean Sample : 1/31 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Library : C:\DATABASE\WILEY7N.L

Peak Number 9 TETRACOSAMETHYLCYCLODODECAS... Concentration Rank 7

R.T. EstConc Area Relative to ISTD R.T.

27.56 0.88 ug/L 448562 Chrysene-dl2 30.34

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 TETRACOSAMETHYLCYCLODODECASILOXA. . . 888 C24H72012Sil2 018919-94-3 72 2 BISTRIMETHYLSILYL N-ACETYL EICOS... 511 C28H57NO3Si2 000000-00-0 72 3 Iron, monocarbonyl-(1,3-butadien... 438 C21H22FeN2O5 109007-87-6 47 4 SILICONE POLYMER 458 C14H4205Si6 000000-00-0 40 Abundance Scan 2699 (27.556 min): 2335.D (-) m/z 73.10 100.00% 73

5000 147 221 355 11 ।. । 11A . . 281 429 27.20 27.40 27.60 27.80 0 TIr p’rer ...1 .A amkaista- m/z 147.10 41.66% m/z—> 50 100 150 200 250 300 350 400 450 500 550 600 650 Abundance#391010: TETRACOSAMETHYLCYCLODODECASILOXANE $$ Cyclod > 73 355

5000 147 221 281 27.20 27.40 27.60 27.80 m/z 221.10 32.29% 415 0 TTtr — — I.I.... 1... 11.... J., m/z—> 50 100 150 200 250 300 350 400 450 500 550 600 650 Abundance#370710: BISTRIMETHYLSILYL N-ACETYL EICOSASPHINGA-4,11-DII • 73 — ‘i T T‘ 27.20 27.40 27.60 27.80 5000 m/z 355.00 23.16% 174 129 337 , 429

'n/z—> 0- 1.390 । .1,11., ‘‘1*t+*1****1****I‘*‘‘I‘ 50 100 150 200 250 300 350 400 450 500 550 600 650 Abundance #350342: Iron, monocarbonyl-(1,3-butadiene-1,4-dicarbonic... 73 ... .7 27.20 27.40 27.60 27.80 m/z 281.00 16.67%

147 221 5000 355 281 429 503

m/z—> 0 „ulanu43..—44, 26 ... 11.577 50 100 150 200 250 300 350 400 450 500 550 600 650 652 ' I " " i “ ' ■ ■ 27.20 27.40 27.60 27.80 ' ■ i ■ ■ ■ ■ i'

2335.D 5080302.M Mon Mar 18 08:31:28 2002 Page 11

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