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GCMS analysis results for sample AE02381, March 2002

Machine-extracted title · confidence 100%

Laboratory report detailing gas chromatography-mass spectrometry analysis of environmental sample AE02381 conducted on March 22, 2002.

NYC-WTC_000010659–000010676

Folder label: “GCMS X 1/31/02 A 3/4/02

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NYC 9/11 Public Portal Document Library Search Compound Report

Data File C:\MSDCHEM\l\DATA\03 04 02\2 3 81.D Vial: 16 Acq On 4 Mar 2002 10:32 pm Operator: McLean Sample 1/31 Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Library : C:\DATABASE\WILEY7N.L

Peak Number 9 TETRACOSAMETHYLCYCLODODECAS..- Concentration Rank 10

R.T. EstConc Area Relative to ISTD R.T.

28.99 0.41 ug/L 177622 Chrysene-dl2 30.34

Hit# of 5 Tentative ID MW MolForm CAS# Qual

I TETRACOSAMETHYLCYCLODODECASILOXA. . . 888 C24H7201Sil 018919-94-3 83 2 BISTRIMETHYLSILYL N-ACETYL EICOS... 511 C28H57NCBSi2 000000-00-0 50 3 Iron, monocarbonyl-(1,3-butadien... 438 C21H22FeN205 109007-87-6 46 4 Trisiloxane, 1,1,1,5,5,5-hexamet... 384 C12H36O4Si 003555-47-3 43 Abundance Scan 2857 (28.990 min): 2381.D (-) Pm/z 73.10 100.00% 73

5000 147 221 281 429 355 T T 1 28.60 28.80 29.00 29.20 29.40 T T

/z—> 0 ■ ■ I • ' H 101 — 50 100 150 200 250 300 350 400 450 500 550 600 650 m/z 147.10 42.69%

Abundance#391010: TETRACOSAMETHYLCYCLODODECASILOXANE $$ Cyclode) 73 355

5000 147 221 281 P-mmmm 28.60 28.80 29.00 29.20 29.40 m/z 221.10 31.61% 415 0- IH T mH — Hr m/z—> 50 100 150 200 250 300 350 400 450 500 550 600 650 Abundance#370710: BISTRIMETHYLSILYL N-ACETYL EICOSASPHINGA-4,11-DIE: 73 .. IA.. 28.60 28.80 29.00 29.20 29.40 ' i' ‘• i ‘ '

5000 m/z 281.00 20.06% 174 129 337 221 281 . 429

miz-> 0- + , .390 Tr TI 1 . i * ! । fi 1111 ii 1111 > n 111111 50 100 150 200 250 300 350 400 450 500 550 600 650 Abundance #350342: Iron, monocarbonyl-(1,3-butadiene-1,4-dicarbonic... 73 i ■ • •' i ■ • ■ ■ i • ‘ 28.60 28.80 29.00 29.20 29.40 • i ■ ■

m/z 355.10 16.33%

147 221 5000 355 281 429 26 ... 503

m/z—> 0- 4. 31741, tnmmmre 1 577 652 50 100 150 200 250 300 350 400 450 500 550 600 650 i ■ • ■ ■ i ■ • I' ‘ ‘ I ‘ 28.60 28.80 29.00 29.20 29.40 • I • ■

2381.D 5080302.M Mon Mar 18 08:33:28 2002 Page 11

NYC-WTC_000010674

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NYC-WTC_000010674Source: NYC Law Department, mirrored locally

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