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GCMS analysis report, sample AE02339, March 22, 2002

Machine-extracted title · confidence 100%

Laboratory analysis report for sample AE02339 conducted on March 22, 2002, listing unknown compounds and surrogates.

NYC-WTC_000010610–000010630

Folder label: “GCMS X 1/31/02 A 3/4/02

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NYC 9/11 Public Portal Document Library Search Compound Report

. Data File C:\MSDCHEM\l\DATA\030402\2339.D Vial: 11 Acq On 4 Mar 2002 6:27 pm Operator: McLean Sample 1/31 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Library : C:\DATABASE\WILEY7N.L

Peak Number 12 TETRACOSAMETHYLCYCLODODECAS... Concentration Rank 10

R.T. EstConc Area Relative to ISTD R.T.

32.82 0.78 ug/L 252236 Perylene-dl2 34.21

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 TETRACOSAMETHYLCYCLODODECASILOXA. . . 888 C24H72012Sil 018919-94-3 87 2 Iron, monocarbonyl-(1,3-butadien... 438 C21H22FeN205 109007-87-6 38 3 3-Isopropoxy-1,1,1,7,7,7-hexamet... 576 C18H52O7ST7 071579-69-6 35 4 BISTRIMETHYLSILYL N-ACETYL EICOS... 511 C28H57NO3Si2 000000-00-0 35 Abundance Scan 3279 (32.817 min): 2339.D (-) m/z 73.10 100.00% 73

147 5000 221

281 355 429 32.40 32.60 32.80 33.00 33.20 — J — m/z 147.10 55.68% 0 TpH TI m/z-> 50 100 150 200 250 300 350 400 450 500 550 600 650 Abundance#391010: TETRACOSAMETHYLCYCLODODECASILOXANE $$ Cyclod ) 73 355

5000 147 221 281 TTMT T k T 32.40 32.60 32.80 33.00 33.20 m/z 221.10 47.68% 415 0- ■ ■ ■ i1 ■ TT m —r 111" "I ""I"" I" m/z-> 50 100 150 200 250 300 350 400 450 500 550 600 650 Abundance #350342: Iron, monocarbonyl-(1,3-butadiene-1,4-dicarbonic... 73 32.40 32.60 32.80 33.00 33.20 147 221 23.63% 5000 m/z 281.00 355 281 429 26 111 503 irr auzull 577 652 [ miz-> 0- —44444183 Tmmo 50 100 150 200 250 300 350 400 450 500 550 600 650 Abundance #379639: 3-Isopropoxy-1,1,1,7,7,7-hexamethyI-3,5,5-trls(tr... 73 _AA 32.40 32.60 32.80 33.00 33.20 m/z 207.00 20.14%

5000 147

221 281 2- ... , 0 —H ■ ■ i • ■ .1 l 327 415 519 561 i ■ri ■ * Piv rr' Frri 11 11 i*i 111 > ■ 11 |'ii > > । 11111111 ■ r T T rn/z-> 50 100 150 200 250 300 350 400 450 500 550 600 650 32.40 32.60 32.80 33.00 33.20

2339.D 5080302.M Mon Mar 18 08:32:51 2002 Page 14

NYC-WTC_000010628

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NYC-WTC_000010628Source: NYC Law Department, mirrored locally

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