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GCMS re-analysis results, Sample AD28596, December 2001

Machine-extracted title · confidence 92%

Repeat gas chromatography-mass spectrometry analysis of sample AD28596 after re-extraction, confirming bis(2-Ethylhexyl)phthalate at 0.36 ug/L with improved standard recovery of 89

NYC-WTC_000034908–000034918

Folder label: “GCMS X 11/23/01 A 11/29/01

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C: \HPCHEM\ 1 \DATA\DEC 1001\28596.D Vial: 21 Acq On : 11 Dec 2001 6:14 am Operator: 209 GALOS Sample : gc/ms scan 12/3 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 2-Propanol, 1-(2-methoxy-l-met Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

11.34 1.05 ug/1 257829 1,4-Dichlorobenzene-d4 11.67

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Propanol, 1-(2-methoxy-1-methylet 148 C7H16O3 020324-32-7 78 2 2-Butanol, 3,3'-oxybis- 162 C8H18O3 054305-61-2 64 3 1-Propanol, 2-(2-hydroxypropoxy)- 134 C6H14O3 000106-62-7 59 4 2-Propanol, 1-(2-methoxypropoxy)- 148 C7H1603 013429-07-7 50 Abundance Scan 685 (11.335 min): 28596.D (-) m/z 59.05 10C .00% 59

miz-? 5000

' i 1 1 1 1 i • 20 30 39 40 51 । 45

----- i'1 ■ । 85 50 60 70 80 90 73 103

130 ' 1 1 । ■ 111 — 1 i 1 1 ' ' I ' 1 ' 1 I 1 ' ' 1 i ' 100 110 120 130 140 11.00 11,20 11.40 11.60 m/ z T T

45.05 M__ -______ 47.83% Abundance #9238: 2-Propanol, 1-(2-methoxy-1 -methylethoxy} 59

5000

31 45 73 103 MX TT i 1 TT ■ i • ■ ■ ■ I'1 ' 1 1 | TIT T | 11.00 11.20 11.40 11.60 m/z 103.05 33.32%

m/z-> 20 .. —30P40 50 —PHIT 11 160 70 I ' ' TI I TII 80 90 100 110 120 130 130 140 Abundance #12859; 2-Butanol, 3,3°-oxybis- 59 TTTTuuunaT 1100 1120 11.40 11.60 5000 31 45 m/z 73.00_ 28.38% 103

miz-? Abundance 20 • i ■ ■ 1 ■ i • ■ ' ' i ' 30 40 tPt U ’ ■ ' ' i ■ 1 ' ' i ■ ' ' ' i ' 1 ’ ■ i ■ ' ■ ■ i ■ 1 ' TIT134 50 60 70 80 90 100.. 110 120 । । । । । 130 140 A A #6086:1-Propanol, 2-(2-hydroxypropoxy)- ' ' T Pr i 1 ' ' ' i ' ’ ■ ' i ■ ' ■ ' i 59 11.00 11.20 11.40 11.60 m/z 41.05 23.72% 5000 31 45 103

'20PP ....... ........ hTr 75 89 ' i ■ ■ ■ ■ i ■ ■ ■ ■ i' • ■11'1 ■ ■ । ■1 ■ ■ ir' ■ ' i ■ ■ • ■ । ■ —T TPITTTTF m/z—> 30 40 50 (60 70 80 90 100 110 120 130 140 11.00 11.20 11.40 11.60

28596.D GCMS1126.M Fri Dec 14 16:47:09 2001 Page 2

NYC-WTC_000034916

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NYC-WTC_000034916Source: NYC Law Department, mirrored locally

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