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GC/MS analysis results for sample AE11415, May 28 2002

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Laboratory report documenting gas chromatography/mass spectrometry analysis of sample AE11415 conducted on May 28, 2002.

NYC-WTC_000025304–000025318

Folder label: “GCMS X 5/15/02 A 5/18/02

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NYC 9/11 Public Portal Document LLOLdLY DdrCII toMpOuIC KEpOLL

Data File : C:\MSDCHEM\1\DATA\051702\11414.D Vial: 23 Acq On : 18 May 2002 7:32 am Operator: Mclean Sample : 5/15 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 7 Phenanthrene-diO Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

23.11 0.45 ug/L 483567 Phenant hranene - dl 0 22.95

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Phenanthrene-dl0 188 C14D10 001517-22-2 94 2 Anthracene-dlO- 188 C14D10 001719-06-8 91 3 Pentacyclo[7.3.1.1.(4,12).0(2,7)... 188 C14H20 1000215-61-8 53 4 2-Quinolinecarboxaldehyde, 8-hyd... 188 C10H8N2O2 005603-22-5 40 Abundance Scan 3409 (23.109 min): 11414.D (-3401) (-) m/z 188.10 100.00% 188

5000 ----- 80 42 54 66 , 94 . 158 22.80 23.00 23.20 23.40 11 146 III m/z 189.10 0 ' i1 ‘'1 r " ' i' m f M r . | ■ I I V j . H I | ! ■ J I b 1 I I I I I I I I I I I I I I I I I P I I I j I I I I I I I I > I I I I I I I T’T 15.13% m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79827: Phenanthrene-d10 188

------ 5000 22.80 23.00 23.20 23.40 m/z 80.10 14.20% 80 94 160 66 30 42 52 11 108 118 132 0 ' i' " ' i" ‘11'1" 11' " i11" i11 HHH I I r rt1 i t p i i i p । । q I j j i 146,,4,.179179il,.11 m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79826: Anthracene-d10- 188

22.80 23.00 23.20 23.40 5000 m/z 184.05 12.68%

80 94 160

m/z—> 17 30 66 0 W)22——m01———11————1—4—1138 108 118 132 146—+1791794 42 52 HH 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 I H | I I I l pl I 1-4 1 1 U Abundance #79715: Pentacyclo[7.3.1.1 .(4,12).0(2,7).0(6,11 )]tetradeca... 188 22.80 23.00 23.20 23.40 m/z 94.10 10.80%

5000 79 91 55 67 131 105 117 0 ' i " " I " " i" " i " " Il ' i ’ 11 " i ■ Ms 11' 1111 ■ 1111'i m 11 l—l | 145 159 173 ..... 1................... 1 ' i ■ 1 1 1T' ■ I ■ ‘ 1 1 i ' 1 1 1-i m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 22.80 23.00 23.20 23.40

11414.D 050102.M Tue May 21 15:57:12 2002 Page 9

NYC-WTC_000025317

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