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GCMS analysis results for sample AE10900, May 21 2002

Machine-extracted title · confidence 100%

Laboratory report detailing GCMS analysis of sample AE10900 conducted on May 21, 2002, including surrogate recovery data.

NYC-WTC_000024141–000024152

Folder label: “GCMS X 5/10/02 A 5/16/02

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Data File : C:\MSDCHEM\l\DATA\051602\10900.D Vial: 13 Acq On : 17 May 2002 12:19 am Operator: Mclean Sample : 5/10 eh Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 4 Phenanthrene-diO Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

23.11 0.52 ug/L 571837 Phenant hranene - dl 0 22.95

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Phenanthrene-diO 188 C14D10 001517-22-2 72 2 Anthracene-d10- 188 C14D10 001719-06-8 50 3 Naphthalene, 1,7-dimethoxy- 188 C12H1202 005309-18-2 40 4 4H-Pyrido[1,2-a]pyrimidin-4-one, ... 188 C11H12N2O 057773-19-0 38 Abundance Scan 3408 (23.103 min): 10900.D (-3403) (-) m/z 188.10 100.00% 188

5000

80 94 22.80 23.00 23.20 23.40 43 52 66 । 158 I 0- I. TTTTTTTTTTT’TTT-T- 1....... . ................. ......... 'I lb "' r ■'' i’W'1"" m/ z 80.20 17.05% mfe-> 10 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 Abundance #79827: Phenanthrene-d10 188

- 5000 22.80 23.00 23.20 23.40 m/z 184.10 14.87% 80 94 160 30 42 52 66 mfe-> 0 IWTTTTTTTTTTTTH TTtuHr .I 108118 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 132 146 7.144.79172).. Abundance #79826: Anthracene-d 10- 188 - 22.80 23.00 23.20 23.40 5000 m/ z 94.10 13.66%

66 80 94 160 17 30 42 52 , . J 108118 132 146 11, 170179, 0 TIWWTTPTTTTTTTHT 11 11 I I [ 11 11 IJ J I; 111 I ] 1111 [ 11 I r I H H [I i h | IJ 1-11 I I ’ 11 I 11 11 111’l’l* Ilir mlz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79804: Naphthalene, 1,7-dimethoxy- 173 188 22.80 23.00 23.20 23.40 m/z 189.10 10.58%

5000 102 115 145 51 63 75 ..... |....... . 158 130 -

/z-> 0 ---H 1111.... । J 1. 10 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 111 “ 22.80 23.00 23.20 23.40

10900.D 050102.M Fri May 17 15:08:17 2002 Page 7

NYC-WTC_000024151

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