GCMS analysis results, sample AE11157, May 22, 2002

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Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\020515\11157.D Vial: 9 Acq On : 15 May 2002 7:43 pm Operator: Nefliu Sample : sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: rteint.e Quant Method : C:\MSDCHEM\1\METHODS\SCAN020507.M (RTE Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1

Peak Number 5 Phenanthrene, 1-methyl- Concentration Rank 4

R.T. EstConc Area Relative to. I STD R.T. 31.09 0.31 ug/1 34159 Phenanthrene-dl0 31.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Phenanthrene, 1-methyl- 192 C15H12 000832-69-9 53 2 Benzene/, 1 -bromo-4-chioro- 190 C6H4BrCl 000106-39-8 53 3 Thiocyanic acid, 2-benzothiazoly ... 192 C8H4N2S2 006011-99-0 53 4 1,5-Naphthalenedithiole 192 C10H8S2 1000223-69-5 53 Abundance Scan 4768 (31.094 min): 11157. D (-4759) (-) m/z 192.15 100.00% 192

5000

96 146 ! m/z-> 20 >' 11111' 111 i'i

40 44 41. I60 80 100 140 160 180 200 220 240 120 229 :332 11—’091’00’100101103001’0n133) 260 280 300 320 30,80 31.00 31.20 31.40 m/z 191.20 17.08% Abundance #125856: Phenanthrene, 1-methyl- 192

5000 -A 30.80 31.00 31.20 31.40 m/z 96.10 15.74% 96 I RR .... 39 63 81 115 139 2. । i । i i i i | i n i p i n 111 । , i ri । i i i i'| i il i | Vi i I i ■ i ■ ■'' i''111 ■ ■ ■ ■ r ■1' i ■ ■ ■ ■ 1 ■ ■ ■ ■ i ‘■ i mfe-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 Abundance #125839: Benzene, 1-bromo-4-chloro- 192

111 30.80 31.00 31.20 31.40 5000 m/z 146.10 13.49% 75 50 96 , , । 28 | , ,n I " ‘if,* FT11 I' I , 131 155 1 ■ i " ' ■ i' " i ■ ■ ■ ■ i' ■ m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 Abundance #80870: Thiocyanic acid, 2-benzothiazolyl ester 192 30.80 31.00 31.20 31.40 m/z 193.10 12.60%

5000

n/z-> 45 " 11" 1111" 20 40 „[480,108..114.100_ 60 80 100 120 140 160 180 200 220 240 260 280 300 320 ‘ i'' " i " " i ■ " ■ r 1111 ■' " i " " 111111 ' 1 i ' ■ ' 1 i ....... 1 30.80 31,00 31.20 31.40

11157.D SCAN020507.M Thu May 16 09:39:02 2002 Page 7

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