GCMS scan report for Method 508, April 2002

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Data File : C:\MSDCHEM\l\DATA\020419\08430.D Vial: 17 Acq On : 19 Apr 2002 11:53 pm Operator: Nefliu Sample : sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\SCAN020418.M (Chemstation Integrator) Title : Method 508 GC/MS Scan Library- : C:\DATABASE\nist98.1 ********************************************************************* Peak Number 6 4-Methyl-2-(4-fluorophenyl)... Concentration Rank 6

R.T. EstConc Area Relative to ISTD R.T.

31.95 0.43 ug/1 918405 Phenanthrene-dl0 31.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 4-Methyl-2-(4-fluorophenyl)pyrim... 188 C11H9FN2 076128-67-1 59 2 4-Methyl-2-(3-fluorophenyl)pyrim... 188 C11H9FN2 076128-66-0 59 3 Phenanthrene-diO 188 C14D10 001517-22-2 56 4 Anthracene-dlO- 188 C14D10 001719-06-8 45 Abundance Scan 4915 (31.957 min): 08430. D (-4905) (-) m/z 188.10 100.00% 188

5000

31.60 31.80 32.00 32.20 .................... .............. ............ 04 m/z 184.10 15.49% miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79745:4-Methyl-2-(4-fluorophenyl)pyrimidine 188

121 5000 31.60 31.80 32.00 32.20 173 m/z 94.10 13.16% 67 94 39 !57 | 75 84 133 146 161 |. 102 ll....... 0 i" " i11 ri i' 111111I P rl‘ | I l'l I | . I I I | I Pl 1'| 1 , I ! | | I 1 l |' 1TI-| 1-1 I I |-| I Pl I I I I i |‘i ri | | |'I n 111 111" " i nfe-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79744:4-Methyl-2-(3-fluorophenyl)pyrimidine 188

31.60 31.80 32.00 32.20 5000 121 m/z80.10 12.77%

173 67 94 391 rl "5011,11,11'11111'" 75 11'111111h ' ।102 134 146 161 |. ll....... 0 ■ i " " i ■ ‘11 r1111111111 111' ’ ’i /z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79827: Phenanthrene-d1 0 188 31.60 31.80 32.00 32.20 m/z 189.20 11.73%

5000

80 94 160 , 42 52 P 0 T I I I I 30 I 102110118 132 146 ,1 170 18Q I | ll ll | l ll » { I I I I fl'H I | ll |-| ITT T J I I I I | t 1 It j I I I 1 | 1 1 | I | |-t 1 ITT 1-1 | l t’l’l’l’i Irram Hl I I I I | m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 31.60 31.80 32.00 32.20

08430.D SCAN020418.M Mon Apr 29 08:29:49 2002 Page 21

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