GCMS analysis log for sample AD30696, Jan 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File C: \HPCHEM\ 1 \DATA\DEC3 101\30696.D Vial: 33 Acq On 1 Jan 2002 7:57 pm Operator: 209 GALOS Sample gems scan 12/19 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 8 Benzene, l-nitro-2-(octyloxy)- Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T.

35.58 1.58 ug/1 223162 Perylene-d12 37.12

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Benzene, 1-nitro-2- (octyloxy) - 251 C14H21NO3 037682-29-4 32 2 Propanedioic acid, hexyl-, diethyl 244 C13H24O4 005398-10-7 27 3 Octane, -ethyl - 142 C10H22 015869-86-0 14 4 Octane, 1,1’-oxybis- 242 C16H34O 000629-82-3 10 Abundance Scan 3326 (35.575 min): 30696.D (-) m/z 185.10 100.00% 185 57

5000 43 70 112 ....... / ... 83 98 | 1 125 143 166 203 240 281 297 35.20 35.40 35.60 35.80 36.00 .nil., .ml, ..t.i l TTTT —0*]mepamp] 1’* ’ I . i Pi ! . » » | : » i . । i i i m/ z 7.00 67.48% miz- 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 (Abundance #34102: Benzene, 1-nitro-2-(octyloxy) 57

71 5000 T 1‘ i 1 ■ 1 ■ i ■ ■ ■ 1 1**1* 112 35.20 35.40 35.60 35.80 36.00 14 139 m/z 70.10 45.26% 221 251 ■ । ■ i ‘ ■ i ■ ■ ■11 ■1 ■ ■ । ‘ । ■ ■ ■ ■ । ■ ■ • ■ ।1 • ■ ■ । ■ • ■' । ■ miz-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 Abundance #32687: Propanedioic acid, hexyl-, diethyl ester 57 70 —1PIMTITTTYY 35.20 35.40 35.60 35.80 36.00 5000 m/z 55.00 42.69% 83 112

42 98 109 217 । ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ । m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 Abundance #8095: Octane, 4-ethyl- 57 35.20 35.40 35.60 35.80 36.00 m/z 1.05 40.81% 5000 71

85 98 112 27 42 1 142 ! | • ■ • ‘ | l ■ I*’ ‘1 ■11 •1 miz-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 35.20 35.40 35.60 35.80 36.00

30696.D GCMS1126.M Wed Jan 23 08:37:08 2002 Page 8

NYC-WTC_000018137