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GCMS analysis summary, sample AD27288, Dec 2001

Machine-extracted title · confidence 100%

GCMS analysis report for sample AD27288 showing surrogate recovery and unknown compounds from December 19, 2001.

NYC-WTC_000016096–000016117

Folder label: “GCMS X 12/26/01 A 1/15-1/16/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C: \HPCHEM\ 1 \DATA\JANO 802\27288.D Vial: 26 Acq On 9 Jan 2002 3:42 pm Operator: 209 GALOS Sample gems scan 12/20a Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0103.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 9 Phenanthrene-diO Concentration Rank 14

R.T. EstConc Area Relative to ISTD R.T.

24.95 0.23 ug/1 77927 Phenanthrene-dl0 24.80

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Phenanthrene-d; 2 Anthracene-d10- 6557 188 C14D10 188 C14D10 001517-22-2 001719-06-8 68 64 3 Selenide, ethyl 1-methyl-1-penten-3 188 C8H12Se 025128-48-7 28 4 5(4H)-1soxazolone, 4,4’-bis[3-methy 376 C22H20N2O4 000000-00-0 25 Abundance Scan 2168 (24.950 min): 27288.D (-) m/z 188.10 100.00% 188

5000 80 94 42 52 66 132 160 24.60 24.80 25.00 25.20 ' m—mpHt + PT IrH—PP i • • • ■ i m/z 94.00 24.65% m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance ” #19958: Phenanthrene-d 10 188

5000 24.60 24.80 25.00 25.20

66 8094 ...............160 _ 1 m/z 80.05 20.46%

m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 ‘156' 160 170 180 196' Abundance $191 0-10- 188 ■ ■ i ■ ■ ■ 1 i ■ ' ■ ■ i ■ ■ ■ ■ i ■ । ■ 24.60 24.80 25.00 25.20 5000 m/z 189.10 15.63%

66 80 94 160 “ ■ ‘ I" ' ‘ I ‘ ' I “ " I' ‘'11 ‘1' ‘ 11' ‘' I ‘ ‘' I' “ ' I' ‘‘ I' “ ' I ‘ ‘ I ‘‘ ■ I ‘ ‘ I “ “ I ‘1" I “ m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #19733: Selenide, ethyl 1-methyl-1-penten-3-ynyl / 188 24.60 24.80 25.00 25.20 m/ z 18 .10 14.67% 5000 79 159 145 173

miz-> ‘' I ” ’ ‘ I “ “ I ‘ “ I ’ ‘ ..................................................... I....... !‘*44,444114414154SSAS[SISESSSS[3* 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 I.. ... ,| 190 ............ .... ................................ 24.60 24.80 25.00 25.20

27288.D GCMS1126.M Mon Feb 04 15:23:28 2002 Page 9

NYC-WTC_000016111

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NYC-WTC_000016111Source: NYC Law Department, mirrored locally

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