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GCMS analysis results for sample AD27771, Jan 2002

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Laboratory report documenting GCMS analysis of environmental sample AD27771 conducted on January 3, 2002.

NYC-WTC_000033580–000033592

Folder label: “GCMS X 11/19/01 A 12/19 - 12/20/01

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\HPCHEM\1\DATA\DEC1901\27771.D Vial: 30 Acq On : 19 Dec 2001 7:33 pm Operator: 209 GALOS Sample : gc/msunknown 11/19 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 5 Phenanthrene-diO Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T. 24.98 18.65 ug/1 6944360 Acenaphthene-dl0 20.55

Hit# of 5 / Tentative ID MW MolForm CAS# Qual

1 Phenanthrene-d10 188 C14D10 001517-22-2 98 2 Anthracene-dlO- 188 C14D10 001719-06-8 97 3 Cyclohexanone, phenyl hydra zone 188 C12H16N2 000946-82-7 53 4 Benzene, 1-(1-cyclohexen-l-yl)-4-me 188 C13H160 020758-60-5 36 Abundance..... .. ... ........ ......Scan 2171 (24.978 min): 27771.D(-) m/z 188.10 100.00% 188

5000

80 ........ L —.......... 94 4e( 1 24.60 24.80 25.00 25.20 25.40 42 52 66 TITTTTTTTTHTTTTH ..... 132—146—170. 189 — TT‘ m/z 187.10 19.41% miz-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #19958: Phenanthrene-diO 188

-......... - 5000 24.60 24.80 25.00 25.20 25.40 m/z 80.05 14.76% 6689 ' I m ■ I | ■ । I I | I I > I | I I I I | I I I I J I I ■ I | । I I । | •■■■ | ■■■ I j ■ H । | U II | । I 160 — T‘11111 miz->__ 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #19957 Anthracene-d10- 188 — —————. ,, ।, <,, ।, 24.60 24.80 25.00 25.20 25.40 5000 m/z 189.10 14.65%

66 80 94 160 TTTTTTTTTTTTTTHTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTT miz->___ 30 40 50 60 7080 90 100 110 120 130 140 150 160 170 180 190 200 Abundance ............................. #19927: Cyclohexanone, phenylhydrazone ’ ’ ......... — ------------------------ 188 24.60 24.80 25.00 25.20 25.40 93 m/z 94.00 13.58% 5000 65 106 145 77 | 120 132 1 159 no ■ i" " r CTTTg — 1111 ■ । i ri 1111rgr TT"TTTTTTTTTTTT i" " I' 11111 IInnT—TTTTTTTTTTTETT miz-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 24.60 24.80 25.00 25.20 25.40

27771.D GCMS1126.M Wed Jan 02 12:01:11 2002 Page 5

NYC-WTC_000033591

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NYC-WTC_000033591Source: NYC Law Department, mirrored locally

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