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GCMS analysis results for sample AE11932, June 2002

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Laboratory report documenting GCMS analysis of sample AE11932 conducted on June 5, 2002.

NYC-WTC_000013666–000013694

Folder label: “GCMS X 5/22/02 A 5/23/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\052302\11932.D Vial: 12 Acq On : 23 May 2002 6:56 pm Operator: Mclean Sample : 5/22ad Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 17 Phenanthrene-diO Concentration Rank 18 R.T. EstConc Area Relative to ISTD R.T. 23.07 0.24 ug/L 245226 Phenanthranene-dl0 22.91 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Phenanthrene-diO 188 C14D10 001517-22-2 64V) 2 Anthracene-dlO- 188 C14D10 001719-06-8 45J 1 3 Benzene, 1-bromo-4-methoxy- 186 C7H7BrO 000104-92-7 43 4 7-Tetradecene -5,9-diyne, (E)- 188 C14H20 013304-98-8 9 Abundance Scan 3402 (23.068 min): 11932.D (-3396) (-) m/z 188.10 100.00% 188

5000 94 80 42 52 66 | 22.80 23.00 23.20 23.40 0— rl1111111" I"11111111'11 1’44* m/z 94.10 28.52% miz-> 10 20 30 40 50 60 70 80 90 100110120 130140 150 160 170 180190 Abundance #79827: Phenanthrene-d10 188

5000 22.80 23.00 23.20 23.40 m/z 189.10 20.54% 80 94 160 , 30 42 52 ,, 66 _,| 108118 132 146 I.l 170179, 0 . I | ll . ! | THmHnptm .I| 1। >I[ 1,I. |II II |1 1I>| nz-> 10 20 30 40 50 60 70 80 90 100110120130140150160170180190 Abundance #79826: Anthracene-d10- 188

22.80 23.00 23.20 23.40 5000 m/z 80.10 18.20%

17 30 42 52 66 1 , 108118 132 146 160 170179111 0 n]0—aampon—p—npHTHTn—mmMTHtTT n/z-> 10 20 30 40 50 60 70 80 90 100110 120130140 150 160 170 180190 Abundance #79820: Benzene, 1-bromo-4-methoxy- 188 22.80 23.00 23.20 23.40 m/z 184.10 18.13% 63 143 173 5000 50 77 38 92

m/z—> 0 15 29 , mppm +— ,.107117.. 155 1’919111991700010—0010133307 -IHpr II. 10 20 30 40 50 60 70 80 90 100110 120130140 150 160 170 180 190 22.80 23.00 23.20 23.40

11932.D 052202.M Wed May 29 09:51:38 2002 Page 2 0

NYC-WTC_000013691

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NYC-WTC_000013691Source: NYC Law Department, mirrored locally

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