GCMS analysis report for sample AE01636, March 2002

NYC 9/11 Public Portal Document Library Search Compound Report . Data File : C: \MSDCHEM\1\5973N\02FEB21\01636.D Vial: 5 Acq On : 21 Feb 2002 6:32 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 21, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 6 3-(CYCLOHEX-3'-EN-YL)PROPAN... Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. 5.95 0.36 ug/L 154455 1,4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$... 174 C8H14O4 015745-87-6 40 2 Acetic acid, 3-[1,3]dioxolan-2-y... 174 C8H14O4 000000-00-0 40 3 1-Propene-1-thiol 74 C3H6S 000925-89-3 4 4 N-Ethylformamide $$ N-Formylethy... 73 C3H7NO 000627-45-2 4 Abundance Scan 228 (5.948 min): 01636.D (-) m/z 73.10 100.00% 73

5000 43 • r* • • > i • ■ ■ i ■ • 1 i ■ ■ ■ ■ i ■ 5.60 5.80 6.00 6.20 .........11.55, 87 103 0- ‘ I *4 * ‘ I ‘ ‘ ‘ ‘ 111 * *14 *′* 1 * ’1113 T—********** k‘ m/z 43.10 25.67% niz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #36138:3-(CYCLOHEX-3’-EN-YL)PROPANOL $$ 2-Cyclohexene-1-p... 73

5000 AA • I ’ ‘ I * r • s ‘ * I 1 ' ■ I ' ' ‘ ‘ I ' ‘ ‘ 5.60 5.80 6.00 6.20 43 m/z 45.10 9.16% 27 55 87 174 0- 4 ■ i■"11" ■ ’I TTT rti■ • ■ ■ i"■ ■ 113 i ■ i ■ ■■ ■ i " ■ ■ i■ ■ ■ ■ i■ ■ ■ ■ i ■■ ■ ■ i‘1"i ■ miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #78238: Acetic acid, 3-[1,3]dioxolan-2-ylpropyl ester 70 ............. A........ ' ■ I ‘ ‘ ' I ' ‘ ■ • I ■ ‘ ' I ‘ ‘ ‘ I ' 5.60 5.80 6.00 6.20 5000 m/z 71.00 6.13% 43 27 55 , 87 113 174 0- • i" i “ “ i'11 • 11 “ 111" ■ * i ■ 1 “ ! 1 ‘1111 “ ' I “ “ I 111' “ 1 I " 11 11 11111 " 11 “ " I " “ 1' miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #2002:1-Propene-1-thiol ■ ■ i ' 1 ■ ■ i 1 73 5.60 5.80 6.00 6.20 m/z 69.00 4.58% 5000 43

OmPTTT ।। 1.lli. ।,.5/ .'I',.... i'i1 ’ p ■ ' i ' ' ■ ■ i ■ ■ ■ ■ i 1 ■ 1 ■ i ' ■ ■ 1 i 1

m/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 5.60 5.80 6.00 6.20

01636.D HP022102.M Mon Feb 25 10:55:38 2002 Page 8

NYC-WTC_000010097