GCMS analysis report for sample AE01636, March 2002

NYC 9/11 Public Portal Document Library Search Compound Report . Data File : C:\MSDCHEM\1\5973N\02FEB21\01636.D Vial: 5 Acq On : 21 Feb 2002 6:32 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 21, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L

Peak Number 5 Pyrrolidine (CAS) $$ Prolam... Concentration Rank 7 R.T. EstConc Area Relative to ISTD R.T.

5.03 0.06 ug/L 26035 1,4-Dichlorobenzene-d4 9.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Pyrrolidine (CAS) $$ Prolamine $... 71 C4H9N 000123-75-1 4 2 (Aminomethyl)cyclopropane 71 C4H9N 002516-47-4 4 3 Acetaldoxime $$ (E)-CH3CH=NOH $$... 59 C2H5NO 000107-29-9 4 4 PROPANAL, 2-DEUTERO- 59 C3H5DO 062338-06-1 4 Abundance Scan 147 (5.033 min): 01636.D(-) m/z 71.10 100.00% 71 43

5000 59

53 4.60 4.80 5.00 5.20 5.40 O' i11'11'11 ■ ।1 ■1 ■ t ■ ■ • ■ i1 ■ “ । ■1 ■ । । ‘+1111’17 m/z 43.00 81.29% miz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 Abundance #1475: Pyrrolidine (CAS) $$ Prolamine $$ Azolidine 3$ Buty... 43

5000 LAAAN 4.60 4.80 5.00 5.20 5.40 70 40 m/z 41.10 76.72% 30 0111 ■ ■ ■ * ।■ 11 *1111 Il 37 2530354045505560 65 6770 7580 ’“I""!' niz-> 5’ 10 15 20 Abundance #1489: (Aminomethyl)cyclopropane 43 30 4.60 4.80 5.00 5.20 5.40 5000 m/z 59.00 46.04%

27 71

miz-> 01 5 m 10 15 25 30 35 20 34 38 54 , 68 | ' ' ' 11 1 11 1 1 1TTT —mH1 ■ » |v .. । . 40 45 50 55 60 65 70 75 80 Abundance #644: Acetaldoxime $$ (E)-CH3CH=NOH $$ Acetaldehyde oxime ... 15 59 । . । 1 4.60 4.80 5.00 5.20 5.40 41 m/z 44.00 24.05% 44 5000 J A N 27 30

m/z—> 0- ■ ■ i 133 T-|-t-n-rp-r 5 10 15 20 25 30 35 40 45 1' " 111' ” ir'' 50 55 I ‘ ‘ ‘ ‘ I ' ‘ ‘ ' I ' ‘ “ I ‘ ‘ ‘ ' I ' 60 65 70 75 80 W 4.60 4.80 ' 1 i ■ ■ • ' I* 5.00 5.20 1 ■ 1 1 5.40

01636.D HP022102.M Mon Feb 25 10:55:38 2002 Page 7

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